A | B | C | D | E | F | G | H | I | |
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1 | Attachment B - Emission Calculations | ||||||||
2 | Table B-1: Emissions from the RTO | ||||||||
4 | Toxics Emission Unit ID: | TO-01 | |||||||
5 | Emission Point: | RTO1 | |||||||
6 | Description: | Regenerative Thermal Oxidizer (RTO) controlling Refinery, Oil Polishing System (OPS) and Sulfonation | |||||||
8 | Max. Operating Parameters: | References | |||||||
9 | Ref. 1: January 30-31, 2020 Source Test | ||||||||
10 | Hours per Day | 24 | hrs/day | Ref. 1b: January 26-27, 2022 Source Test (Naphthalene result multiplied by a factor of 10 due to instrument saturation reported by lab) | |||||
11 | Hours per Year | 8760 | hrs/year | Ref. 2: Emissions Estimation Protocol for Petroleum Refineries, Version 3, Appendix D—Emission Factors for Combustion Sources, Table D-9a. Summary of Data for Emission Factor Development – Heaters Firing Fuel Oil | |||||
12 | Ref. 2a: SCAQMD Reporting Procedures for AB2588 Facilities Reporting their Quadrennial Air Toxic Emission Inventory in the Annual Emission Reporting Program, Appendix B-1, Table B-2. | ||||||||
13 | HTR-3 Daily Distillate Consumption | 2,100 | gal/day | Ref. 3: Emissions Estimation Protocol for Petroleum Refineries, Version 3, Appendix D—Emission Factors for Combustion Sources, Table D-11a. Summary of Data for Emission Factor Development – Heaters Firing Refinery Fuel Gas | |||||
14 | HTR-3 Daily Distillate Consumption | 766,500 | gal/yr | Ref. 4: SCAQMD Reporting Procedures for AB2588 Facilities Reporting their Quadrennial Air Toxic Emission Inventory in the Annual Emission Reporting Program, Appendix B-1, Table B-1. | |||||
16 | Refinery Vac System Flow Rate | 57 | ACFM | ||||||
17 | Refinery Vac System Air Temp | 140 | F | ||||||
19 | OPS Flow Rate | 1,398 | lb/hr | ||||||
20 | OPS Temp | 140 | F | ||||||
21 | Air Density @ Temp | 0.06619 | lb/ft3 | ||||||
22 | OPS Air Flow Rate | 352 | ACFM | ||||||
24 | Sulfonation Flow Rate | 750 | ACFM | ||||||
25 | Sulfonation Temp | 140 | F | ||||||
27 | Total System "Refinery Gas" Air Flow Rate | 1,159 | ACFM | ||||||
29 | Thermal Oxidizer Burner Rating | 1.0 | MMBtu/hr | ||||||
30 | Natural Gas HHV | 1,020 | Btu/ft3 | ||||||
32 | RTO Stack Volumetric Flow Rate | 3,071 | dscfm | (Jan. 20 ST - metals run) | |||||
34 | Calculation Table | ||||||||
36 | Emission Factor Set | TAC | CAS # | Emission Factor | Units | Emissions (lb/year) | Emissions (lb/day) | EF Reference | Notes |
37 | Set 1 | Antimony and compounds | 7440-36-0 | 3.80E-05 | lb/hr | 3.33E-01 | 9.12E-04 | Ref. 1 | One ND |
38 | Arsenic and compounds | 7440-38-2 | 3.00E-04 | lb/hr | 2.63E+00 | 7.20E-03 | Ref. 1 | ||
39 | Barium and compounds | 7440-39-3 | 1.30E-04 | lb/hr | 1.14E+00 | 3.12E-03 | Ref. 1 | ||
40 | Beryllium and compounds | 7440-41-7 | 1.50E-06 | lb/hr | 1.31E-02 | 3.60E-05 | Ref. 1 | Three ND | |
41 | Cadmium and compounds | 7440-43-9 | 3.00E-06 | lb/hr | 2.63E-02 | 7.20E-05 | Ref. 1 | Three ND | |
42 | Chromium VI, chromate, and dichromate particulate | 18540-29-9 | 1.60E-04 | lb/hr | 1.40E+00 | 3.84E-03 | Ref. 1 | ||
43 | Cobalt and compounds | 7440-48-4 | 6.20E-06 | lb/hr | 5.43E-02 | 1.49E-04 | Ref. 1 | ||
44 | Copper and compounds | 7440-50-8 | 8.30E-05 | lb/hr | 7.27E-01 | 1.99E-03 | Ref. 1 | ||
45 | Lead and compounds | 7439-92-1 | 2.10E-04 | lb/hr | 1.84E+00 | 5.04E-03 | Ref. 1 | ||
46 | Manganese and compounds | 7439-96-5 | 3.00E-04 | lb/hr | 2.63E+00 | 7.20E-03 | Ref. 1 | ||
47 | Mercury and compounds | 7439-97-6 | 1.70E-05 | lb/hr | 1.49E-01 | 4.08E-04 | Ref. 1 | ||
48 | Nickel compounds, insoluble | C365 | 1.10E-04 | lb/hr | 9.64E-01 | 2.64E-03 | Ref. 1 | ||
49 | Phosphorus and compounds | 7723-14-0 | 7.10E-01 | lb/hr | 6.22E+02 | 1.70E+00 | Ref. 1 | ||
50 | Selenium and compounds | 7782-49-2 | 1.40E-04 | lb/hr | 1.23E+00 | 3.36E-03 | Ref. 1 | One ND | |
51 | Silver and compounds | 7440-22-4 | 3.20E-05 | lb/hr | 2.80E-01 | 7.68E-04 | Ref. 1 | ||
52 | Thallium and compounds | 7440-28-0 | 7.50E-05 | lb/hr | 6.57E-01 | 1.80E-03 | Ref. 1 | Three ND | |
53 | Zinc and compounds | 7440-66-6 | 1.40E-03 | lb/hr | 1.23E+00 | 3.36E-02 | Ref. 1 | ||
54 | Set 1b | 1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin (HpCDD) | 35822-46-9 | 1.54E-09 | lb/hr | 1.35E-05 | 3.70E-08 | Ref. 1b | |
55 | Octachlorodibenzo-p-dioxin (OCDD) | 3268-87-9 | 3.66E-09 | lb/hr | 3.21E-05 | 8.78E-08 | Ref. 1b | ||
56 | 2,3,7,8-Tetrachlorodibenzofuran (TcDF) | 51207-31-9 | 7.27E-10 | lb/hr | 6.37E-06 | 1.75E-08 | Ref. 1b | ||
57 | Acenaphthene | 83-32-9 | 2.15E-05 | lb/hr | 1.88E-01 | 5.16E-04 | Ref. 1b | ||
58 | Acenaphthylene | 208-96-8 | 5.31E-05 | lb/hr | 4.65E-01 | 1.27E-03 | Ref. 1b | ||
59 | Anthracene | 120-12-7 | 2.92E-05 | lb/hr | 2.56E-01 | 7.01E-04 | Ref. 1b | ||
60 | Benz[a]anthracene | 56-55-3 | 1.52E-05 | lb/hr | 1.33E-01 | 3.65E-04 | Ref. 1b |
61 | Benzo[a]pyrene | 50-32-8 | 2.46E-07 | lb/hr | 2.16E-03 | 5.91E-06 | Ref. 1b | ||
---|---|---|---|---|---|---|---|---|---|
62 | Benzo[b]fluoranthene | 205-99-2 | 7.55E-06 | lb/hr | 6.61E-02 | 1.81E-04 | Ref. 1b | ||
63 | Benzo[e]pyrene | 192-97-2 | 1.85E-06 | lb/hr | 1.62E-02 | 4.44E-05 | Ref. 1b | ||
64 | Benzo[g,h,i]perylene | 191-24-2 | 1.02E-06 | lb/hr | 8.94E-03 | 2.45E-05 | Ref. 1b | ||
65 | Benzo[k]fluoranthene | 207-08-9 | 1.47E-06 | lb/hr | 1.29E-02 | 3.53E-05 | Ref. 1b | ||
66 | Chrysene | 218-01-9 | 2.26E-05 | lb/hr | 1.98E-01 | 5.42E-04 | Ref. 1b | ||
67 | Fluoranthene | 206-44-0 | 6.64E-05 | lb/hr | 5.82E-01 | 1.59E-03 | Ref. 1b | ||
68 | Fluorene | 86-73-7 | 8.99E-05 | lb/hr | 7.88E-01 | 2.16E-03 | Ref. 1b | ||
69 | 2-Methyl naphthalene | 91-57-6 | 2.14E-03 | lb/hr | 1.87E+00 | 5.14E-02 | Ref. 1b | ||
70 | Naphthalene | 91-20-3 | 2.80E-02 | lb/hr | 2.45E+01 | 6.72E-01 | Ref. 1b | ||
71 | Phenanthrene | 85-01-8 | 2.60E-04 | lb/hr | 2.28E+00 | 6.24E-03 | Ref. 1b | ||
72 | Pyrene | 129-00-0 | 4.43E-05 | lb/hr | 3.88E-01 | 1.06E-03 | Ref. 1b | ||
73 | PCB-8 [2,4'-dichlorobiphenyl] | 34883-43-7 | 1.20E-07 | lb/hr | 1.05E-03 | 2.88E-06 | Ref. 1b | ||
74 | PCB 18 [2,2',5-trichlorobiphenyl] | 37680-65-2 | 7.94E-08 | lb/hr | 6.96E-04 | 1.91E-06 | Ref. 1b | ||
75 | PCB-28 [2,4,4'-trichlorobiphenyl] | 7012-37-5 | 6.71E-08 | lb/hr | 5.88E-04 | 1.61E-06 | Ref. 1b | ||
76 | PCB-44 [2,2',3,5'-tetrachlorobiphenyl] | 41464-39-5 | 2.69E-08 | lb/hr | 2.36E-04 | 6.46E-07 | Ref. 1b | ||
77 | PCB-52 [2,2',5,5'-tetrachlorobiphenyl] | 35693-99-3 | 2.82E-08 | lb/hr | 2.47E-04 | 6.77E-07 | Ref. 1b | ||
78 | PCB-66 [2,3',4,4'-tetrachlorobiphenyl] | 32598-10-0 | 1.35E-08 | lb/hr | 1.18E-04 | 3.24E-07 | Ref. 1b | ||
79 | PCB 77 [3,3',4,4'-tetrachlorobiphenyl] | 32598-13-3 | 1.65E-09 | lb/hr | 1.45E-05 | 3.96E-08 | Ref. 1b | ||
80 | PCB 81 [3,4,4',5-tetrachlorobiphenyl] | 70362-50-4 | 1.42E-10 | lb/hr | 1.24E-06 | 3.40E-09 | Ref. 1b | ||
81 | PCB-101 [2,2',4,5,5'-pentachlorobiphenyl] | 37680-73-2 | 1.37E-08 | lb/hr | 1.20E-04 | 3.29E-07 | Ref. 1b | ||
82 | PCB 105 [2,3,3',4,4'-pentachlorobiphenyl] | 32598-14-4 | 3.26E-09 | lb/hr | 2.86E-05 | 7.82E-08 | Ref. 1b | ||
83 | PCB 118 [2,3',4,4',5-pentachlorobiphenyl] | 31508-00-6 | 8.28E-09 | lb/hr | 7.25E-05 | 1.99E-07 | Ref. 1b | ||
84 | PCB 123 [2,3',4,4',5'-pentachlorobiphenyl] | 65510-44-3 | 2.12E-10 | lb/hr | 1.85E-06 | 5.08E-09 | Ref. 1b | ||
85 | PCB-128 [2,2',3,3',4,4'-hexachlorobiphenyl] | 38380-07-3 | 6.83E-10 | lb/hr | 5.98E-06 | 1.64E-08 | Ref. 1b | ||
86 | PCB-138 [2,2',3,4,4',5'-hexachlorobiphenyl] | 35065-28-2 | 5.53E-09 | lb/hr | 4.84E-05 | 1.33E-07 | Ref. 1b | ||
87 | PCB-153 [2,2',4,4',5,5'-hexachlorobiphenyl] | 35065-27-1 | 4.98E-09 | lb/hr | 4.36E-05 | 1.20E-07 | Ref. 1b | ||
88 | PCB 156 [2,3,3',4,4',5-hexachlorobiphenyl] | 38380-08-4 | 4.57E-10 | lb/hr | 4.01E-06 | 1.10E-08 | Ref. 1b | ||
89 | PCB 167 [2,3',4,4',5,5'-hexachlorobiphenyl] | 52663-72-6 | 1.54E-10 | lb/hr | 1.35E-06 | 3.69E-09 | Ref. 1b | ||
90 | PCB 169 [3,3',4,4',5,5'-hexachlorobiphenyl] | 32774-16-6 | 3.56E-10 | lb/hr | 3.12E-06 | 8.54E-09 | Ref. 1b | ||
91 | PCB-170 [2,2',3,3',4,4',5-heptachlorobiphenyl] | 35065-30-6 | 5.54E-10 | lb/hr | 4.85E-06 | 1.33E-08 | Ref. 1b | ||
92 | PCB-180 [2,2',3,4,4',5,5'-heptachlorobiphenyl] | 35065-29-3 | 2.09E-09 | lb/hr | 1.83E-05 | 5.02E-08 | Ref. 1b | ||
93 | PCB-187 [2,2',3,4',5,5',6-heptachlorobiphenyl] | 52663-68-0 | 8.76E-10 | lb/hr | 7.68E-06 | 2.10E-08 | Ref. 1b | ||
94 | Polychlorinated biphenyls (PCBs) | 1336-36-3 | 1.23E-06 | lb/hr | 1.08E-02 | 2.95E-05 | Ref. 1b | ||
95 | Set 2 | Acetaldehyde | 75-07-0 | 5.43E-03 | lb/Mgal | 4.16E+00 | 1.14E-02 | Ref. 2 | |
96 | Acrolein | 107-02-8 | 5.98E-03 | lb/Mgal | 4.58E+00 | 1.26E-02 | Ref. 2 | ||
97 | Benzene | 71-43-2 | 8.47E-02 | lb/Mgal | 6.49E+00 | 1.78E-01 | Ref. 2 | ||
98 | 1,3-Butadiene | 106-99-0 | 1.95E-01 | lb/Mgal | 1.49E+01 | 4.10E-01 | Ref. 2 | ||
99 | Chloroform | 67-66-3 | 8.63E-02 | lb/Mgal | 6.61E+00 | 1.81E-01 | Ref. 2 | ||
100 | 2-Chloronaphthalene | 91-58-7 | 1.17E-04 | lb/Mgal | 8.97E-02 | 2.46E-04 | Ref. 2 | ||
101 | Formaldehyde | 50-00-0 | 3.80E-02 | lb/Mgal | 2.91E+00 | 7.98E-02 | Ref. 2 | ||
102 | Propylene | 115-07-1 | 1.52E-01 | lb/Mgal | 1.17E+01 | 3.19E-01 | Ref. 2 | ||
103 | Toluene | 108-88-3 | 9.99E-02 | lb/Mgal | 7.66E+00 | 2.10E-01 | Ref. 2 | ||
104 | Xylene (mixture), including m-xylene, o-xylene, p-xylene | 1330-20-7 | 1.92E-01 | lb/Mgal | 1.47E+01 | 4.03E-01 | Ref. 2 | ||
105 | Hydrochloric acid | 7647-01-0 | 1.86E+00 | lb/Mgal | 1.43E+02 | 3.91E+00 | Ref. 2a | ||
106 | Set 3 | Acetaldehyde | 75-07-0 | 1.95E-01 | lb/MMCF | 1.19E+01 | 3.25E-01 | Ref. 3 | |
107 | Benzene | 71-43-2 | 8.42E-01 | lb/MMCF | 5.13E+01 | 1.41E+00 | Ref. 3 | ||
108 | Ethyl benzene | 100-41-4 | 3.04E-01 | lb/MMCF | 1.85E+01 | 5.07E-01 | Ref. 3 | ||
109 | Formaldehyde | 50-00-0 | 1.51E+00 | lb/MMCF | 9.20E+01 | 2.52E+00 | Ref. 3 | ||
110 | Hydrogen Sulfide | 7783-06-4 | 4.05E+00 | lb/MMCF | 2.47E+02 | 6.76E+00 | Ref. 3 |
111 | Phenol | 108-95-2 | 6.96E-02 | lb/MMCF | 4.24E+00 | 1.16E-01 | Ref. 3 | ||
---|---|---|---|---|---|---|---|---|---|
112 | Phosphorus and compounds | 7723-14-0 | 7.21E-03 | lb/MMCF | 4.39E+00 | 1.20E-02 | Ref. 3 | ||
113 | Propylene | 115-07-1 | 2.05E-02 | lb/MMCF | 1.25E+00 | 3.42E-02 | Ref. 3 | ||
114 | Toluene | 108-88-3 | 1.37E+00 | lb/MMCF | 8.35E+01 | 2.29E+00 | Ref. 3 | ||
115 | Xylene (mixture), including m-xylene, o-xylene, p-xylene | 1330-20-7 | 3.74E-01 | lb/MMCF | 2.28E+01 | 6.24E-01 | Ref. 3 | ||
116 | Set 4 | Benzene | 71-43-2 | 8.00E-02 | lb/MMCF | 6.87E-01 | 1.88E-03 | Ref. 4 | Emissions from natural gas combustion in TO. |
117 | Formaldehyde | 50-00-0 | 1.70E-01 | lb/MMCF | 1.46E+00 | 4.00E-03 | Ref. 4 | ||
118 | Acetaldehyde | 75-07-0 | 4.30E-02 | lb/MMCF | 3.69E-01 | 1.01E-03 | Ref. 4 | ||
119 | Acrolein | 107-02-8 | 2.70E-02 | lb/MMCF | 2.32E-01 | 6.35E-04 | Ref. 4 | ||
120 | Ammonia | 7664-41-7 | 3.20E+00 | lb/MMCF | 2.75E+01 | 7.53E-01 | Ref. 4 | ||
121 | Ethyl benzene | 100-41-4 | 9.50E-02 | lb/MMCF | 8.16E-01 | 2.24E-03 | Ref. 4 | ||
122 | Hexane | 110-54-3 | 6.30E-02 | lb/MMCF | 5.41E-01 | 1.48E-03 | Ref. 4 | ||
123 | Toluene | 108-88-3 | 3.66E-01 | lb/MMCF | 3.14E+00 | 8.61E-03 | Ref. 4 | ||
124 | Xylene (mixture), including m-xylene, o-xylene, p-xylene | 1330-20-7 | 2.72E-01 | lb/MMCF | 2.34E+00 | 6.40E-03 | Ref. 4 | ||
125 | Zinc and compounds | 7440-66-6 | 2.90E-01 | lb/MMCF | 2.49E+00 | 6.82E-03 | Ref. 4 | ||
126 | Totals | 1421.4625 | 3.894 | ||||||
128 | Emissions Summary | ||||||||
130 | TAC | CAS # | lb/yr | lb/day | |||||
131 | Antimony and compounds | 7440-36-0 | 3.33E-01 | 9.12E-04 | |||||
132 | Arsenic and compounds | 7440-38-2 | 2.63E+00 | 7.20E-03 | |||||
133 | Barium and compounds | 7440-39-3 | 1.14E+00 | 3.12E-03 | |||||
134 | Beryllium and compounds | 7440-41-7 | 1.31E-02 | 3.60E-05 | |||||
135 | Cadmium and compounds | 7440-43-9 | 2.63E-02 | 7.20E-05 | |||||
136 | Chromium VI, chromate, and dichromate particulate | 18540-29-9 | 1.40E+00 | 3.84E-03 | |||||
137 | Cobalt and compounds | 7440-48-4 | 5.43E-02 | 1.49E-04 | |||||
138 | Copper and compounds | 7440-50-8 | 7.27E-01 | 1.99E-03 | |||||
139 | Lead and compounds | 7439-92-1 | 1.84E+00 | 5.04E-03 | |||||
140 | Manganese and compounds | 7439-96-5 | 2.63E+00 | 7.20E-03 | |||||
141 | Mercury and compounds | 7439-97-6 | 1.49E-01 | 4.08E-04 | |||||
142 | Nickel compounds, insoluble | C365 | 9.64E-01 | 2.64E-03 | |||||
143 | Phosphorus and compounds | 7723-14-0 | 6.22E+02 | 1.71E+00 | |||||
144 | Selenium and compounds | 7782-49-2 | 1.23E+00 | 3.36E-03 | |||||
145 | Silver and compounds | 7440-22-4 | 2.80E-01 | 7.68E-04 | |||||
146 | Thallium and compounds | 7440-28-0 | 6.57E-01 | 1.80E-03 | |||||
147 | Zinc and compounds | 7440-66-6 | 1.48E+00 | 4.04E-02 | |||||
148 | 1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin (HpCDD) | 35822-46-9 | 1.35E-05 | 3.70E-08 | |||||
149 | Octachlorodibenzo-p-dioxin (OCDD) | 3268-87-9 | 3.21E-05 | 8.78E-08 | |||||
150 | 2,3,7,8-Tetrachlorodibenzofuran (TcDF) | 51207-31-9 | 6.37E-06 | 1.75E-08 | |||||
151 | Acenaphthene | 83-32-9 | 1.88E-01 | 5.16E-04 | |||||
152 | Acenaphthylene | 208-96-8 | 4.65E-01 | 1.27E-03 | |||||
153 | Anthracene | 120-12-7 | 2.56E-01 | 7.01E-04 | |||||
154 | Benz[a]anthracene | 56-55-3 | 1.33E-01 | 3.65E-04 | |||||
155 | Benzo[a]pyrene | 50-32-8 | 2.16E-03 | 5.91E-06 | |||||
156 | Benzo[b]fluoranthene | 205-99-2 | 6.61E-02 | 1.81E-04 | |||||
157 | Benzo[e]pyrene | 192-97-2 | 1.62E-02 | 4.44E-05 | |||||
158 | Benzo[g,h,i]perylene | 191-24-2 | 8.94E-03 | 2.45E-05 | |||||
159 | Benzo[k]fluoranthene | 207-08-9 | 1.29E-02 | 3.53E-05 | |||||
160 | Chrysene | 218-01-9 | 1.98E-01 | 5.42E-04 | |||||
161 | Fluoranthene | 206-44-0 | 5.82E-01 | 1.59E-03 | |||||
162 | Fluorene | 86-73-7 | 7.88E-01 | 2.16E-03 |
163 | 2-Methyl naphthalene | 91-57-6 | 1.87E+00 | 5.14E-02 | |||||
---|---|---|---|---|---|---|---|---|---|
164 | Naphthalene | 91-20-3 | 2.45E+01 | 6.72E-01 | |||||
165 | Phenanthrene | 85-01-8 | 2.28E+00 | 6.24E-03 | |||||
166 | Pyrene | 129-00-0 | 3.88E-01 | 1.06E-03 | |||||
167 | PCB-8 [2,4'-dichlorobiphenyl] | 34883-43-7 | 1.05E-03 | 2.88E-06 | |||||
168 | PCB 18 [2,2',5-trichlorobiphenyl] | 37680-65-2 | 6.96E-04 | 1.91E-06 | |||||
169 | PCB-28 [2,4,4'-trichlorobiphenyl] | 7012-37-5 | 5.88E-04 | 1.61E-06 | |||||
170 | PCB-44 [2,2',3,5'-tetrachlorobiphenyl] | 41464-39-5 | 2.36E-04 | 6.46E-07 | |||||
171 | PCB-52 [2,2',5,5'-tetrachlorobiphenyl] | 35693-99-3 | 2.47E-04 | 6.77E-07 | |||||
172 | PCB-66 [2,3',4,4'-tetrachlorobiphenyl] | 32598-10-0 | 1.18E-04 | 3.24E-07 | |||||
173 | PCB 77 [3,3',4,4'-tetrachlorobiphenyl] | 32598-13-3 | 1.45E-05 | 3.96E-08 | |||||
174 | PCB 81 [3,4,4',5-tetrachlorobiphenyl] | 70362-50-4 | 1.24E-06 | 3.40E-09 | |||||
175 | PCB-101 [2,2',4,5,5'-pentachlorobiphenyl] | 37680-73-2 | 1.20E-04 | 3.29E-07 | |||||
176 | PCB 105 [2,3,3',4,4'-pentachlorobiphenyl] | 32598-14-4 | 2.86E-05 | 7.82E-08 | |||||
177 | PCB 118 [2,3',4,4',5-pentachlorobiphenyl] | 31508-00-6 | 7.25E-05 | 1.99E-07 | |||||
178 | PCB 123 [2,3',4,4',5'-pentachlorobiphenyl] | 65510-44-3 | 1.85E-06 | 5.08E-09 | |||||
179 | PCB-128 [2,2',3,3',4,4'-hexachlorobiphenyl] | 38380-07-3 | 5.98E-06 | 1.64E-08 | |||||
180 | PCB-138 [2,2',3,4,4',5'-hexachlorobiphenyl] | 35065-28-2 | 4.84E-05 | 1.33E-07 | |||||
181 | PCB-153 [2,2',4,4',5,5'-hexachlorobiphenyl] | 35065-27-1 | 4.36E-05 | 1.20E-07 | |||||
182 | PCB 156 [2,3,3',4,4',5-hexachlorobiphenyl] | 38380-08-4 | 4.01E-06 | 1.10E-08 | |||||
183 | PCB 167 [2,3',4,4',5,5'-hexachlorobiphenyl] | 52663-72-6 | 1.35E-06 | 3.69E-09 | |||||
184 | PCB 169 [3,3',4,4',5,5'-hexachlorobiphenyl] | 32774-16-6 | 3.12E-06 | 8.54E-09 | |||||
185 | PCB-170 [2,2',3,3',4,4',5-heptachlorobiphenyl] | 35065-30-6 | 4.85E-06 | 1.33E-08 | |||||
186 | PCB-180 [2,2',3,4,4',5,5'-heptachlorobiphenyl] | 35065-29-3 | 1.83E-05 | 5.02E-08 | |||||
187 | PCB-187 [2,2',3,4',5,5',6-heptachlorobiphenyl] | 52663-68-0 | 7.68E-06 | 2.10E-08 | |||||
188 | Polychlorinated biphenyls (PCBs) | 1336-36-3 | 1.08E-02 | 2.95E-05 | |||||
189 | Acetaldehyde | 75-07-0 | 1.23E+01 | 3.38E-01 | |||||
190 | Acrolein | 107-02-8 | 4.82E+00 | 1.32E-02 | |||||
191 | Benzene | 71-43-2 | 5.79E+01 | 1.59E+00 | |||||
192 | 1,3-Butadiene | 106-99-0 | 1.49E+01 | 4.10E-01 | |||||
193 | Chloroform | 67-66-3 | 6.61E+00 | 1.81E-01 | |||||
194 | 2-Chloronaphthalene | 91-58-7 | 8.97E-02 | 2.46E-04 | |||||
195 | Formaldehyde | 50-00-0 | 9.50E+01 | 2.60E+00 | |||||
196 | Propylene | 115-07-1 | 1.29E+01 | 3.53E-01 | |||||
197 | Toluene | 108-88-3 | 9.14E+01 | 2.50E+00 | |||||
198 | Xylene (mixture), including m-xylene, o-xylene, p-xylene | 1330-20-7 | 3.77E+01 | 1.03E+00 | |||||
199 | Hydrochloric acid | 7647-01-0 | 1.43E+02 | 3.91E+00 | |||||
200 | Ethyl benzene | 100-41-4 | 1.86E+01 | 5.10E-01 | |||||
201 | Hydrogen Sulfide | 7783-06-4 | 2.47E+02 | 6.76E+00 | |||||
202 | Phenol | 108-95-2 | 4.24E+00 | 1.16E-01 | |||||
203 | Ammonia | 7664-41-7 | 2.75E+01 | 7.53E-01 | |||||
204 | Hexane | 110-54-3 | 5.41E-01 | 1.48E-03 | |||||
205 | Sulfur Trioxide | 7446-11-9 | 4,713.39 | 12.91 | |||||
206 | Totals | 6134.8519 | 16.8078 |
A | B | C | D | |
---|---|---|---|---|
1 | Attachment B - Emission Calculations | |||
2 | Table B-1a: Emissions from the RTO - Supplemental Sulfur Trioxide Calculation | |||
4 | Toxics Emission Unit ID: | TO-01 | ||
5 | Emission Point: | RTO1 | ||
6 | Description: | Regenerative Thermal Oxidizer (RTO) controlling Refinery, Oil Polishing System (OPS) and Sulfonation | ||
8 | Inputs | |||
10 | Sulfur Dioxide Emission Rate | 4.87 | lb/hr | (Jan. 30-31, 2020 Source Test, OPS bauxite regen process not likely occurring concurrent with testing) |
11 | Sulfur Emission Rate | 2.44 | lb/hr | |
12 | Total Sulfur Present if 5% Oxidized to SO3 | 2.56 | lb/hr | (5% assumption from AP-42, Section 1.3.3.2) |
13 | Sulfur Contribution from Bauxite Regen Process | 1.75 | lb/hr | (Estimated maximum by process vendor) |
14 | Total Sulfur Available to Form Sulfur Trioxide | 4.31 | lb/hr | |
15 | 5% Oxidized to SO3 | 0.22 | lb/hr - S | |
16 | 5% Oxidized to SO3 | 0.54 | lb/hr - SO3 |
A | B | C | D | E | F | G | H | I | J | K | L | M | N | O | P | Q | R | S | T | U | V | W | X | Y | |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
1 | Attachment B - Emission Calculations | ||||||||||||||||||||||||
2 | Table B-2a: VOC Emissions from Fugitive Equipment Leaks | ||||||||||||||||||||||||
3 | |||||||||||||||||||||||||
4 | Toxics Emission Unit ID: | FUG-1 | |||||||||||||||||||||||
5 | Emission Point: | Front, Jail, BO, UO, IT, REF, SULF, LPS1, LPS2, LDARREF, LDARLPSSULF | |||||||||||||||||||||||
6 | Description: | Fugitive Equipment Leaks | |||||||||||||||||||||||
7 | |||||||||||||||||||||||||
8 | |||||||||||||||||||||||||
9 | Area Specific Component Equipment Leak VOC Emissions | ||||||||||||||||||||||||
10 | |||||||||||||||||||||||||
11 | Area/Emission Points | Service Component | Quantity | Emission Factor* (kg/hr/source) | In Service (hours/yr) | In Service (hours/day) | % Leaking | VOC Emissions (lb/yr) | VOC Emission (lb/day) | ||||||||||||||||
12 | Front | Flanges | 80 | 0.00025 | 8760 | 24 | 10% | 38.59 | 0.106 | ||||||||||||||||
13 | Front | Valves | 15 | 0.01090 | 8760 | 24 | 10% | 315.47 | 0.866 | ||||||||||||||||
14 | Front | Pumps | 2 | 0.11400 | 8760 | 24 | 10% | 439.92 | 1.207 | ||||||||||||||||
15 | Jail | Flanges | 200 | 0.00025 | 8760 | 24 | 10% | 96.47 | 0.265 | ||||||||||||||||
16 | Jail | Valves | 40 | 0.01090 | 8760 | 24 | 10% | 841.25 | 2.308 | ||||||||||||||||
17 | Jail | Pumps | 2 | 0.11400 | 8760 | 24 | 10% | 439.92 | 1.207 | ||||||||||||||||
18 | BO | Flanges | 80 | 0.00025 | 8760 | 24 | 10% | 38.59 | 0.106 | ||||||||||||||||
19 | BO | Valves | 20 | 0.01090 | 8760 | 24 | 10% | 420.63 | 1.154 | ||||||||||||||||
20 | BO | Pumps | 2 | 0.11400 | 8760 | 24 | 10% | 439.92 | 1.207 | ||||||||||||||||
21 | UO | Flanges | 30 | 0.00025 | 8760 | 24 | 10% | 14.47 | 0.040 | ||||||||||||||||
22 | UO | Valves | 15 | 0.01090 | 8760 | 24 | 10% | 315.47 | 0.866 | ||||||||||||||||
23 | IT | Flanges | 80 | 0.00025 | 8760 | 24 | 10% | 38.59 | 0.106 | ||||||||||||||||
24 | IT | Valves | 20 | 0.01090 | 8760 | 24 | 10% | 420.63 | 1.154 | ||||||||||||||||
25 | IT | Pumps | 5 | 0.11400 | 8760 | 24 | 10% | 1099.80 | 3.018 | ||||||||||||||||
26 | REF | Flanges | 100 | 0.00025 | 8760 | 24 | 10% | 48.24 | 0.132 | ||||||||||||||||
27 | REF | Valves | 40 | 0.01090 | 8760 | 24 | 10% | 841.25 | 2.308 | ||||||||||||||||
28 | REF | Pumps | 6 | 0.11400 | 8760 | 24 | 10% | 1319.76 | 3.621 | ||||||||||||||||
29 | SULF | Flanges | 100 | 0.00025 | 8760 | 24 | 10% | 48.24 | 0.132 | ||||||||||||||||
30 | SULF | Valves | 40 | 0.01090 | 8760 | 24 | 10% | 841.25 | 2.308 | ||||||||||||||||
31 | SULF | Pumps | 4 | 0.11400 | 8760 | 24 | 10% | 879.84 | 2.414 | ||||||||||||||||
32 | LPS1 | Flanges | 1400 | 0.00025 | 4380 | 24 | 10% | 337.66 | 1.853 | ||||||||||||||||
33 | LPS1 | Valves | 1820 | 0.01090 | 4380 | 24 | 10% | 19138.49 | 105.030 | ||||||||||||||||
34 | LPS2 | Flanges | 250 | 0.00025 | 4380 | 24 | 10% | 60.30 | 0.331 | ||||||||||||||||
35 | LPS2 | Valves | 70 | 0.01090 | 4380 | 24 | 10% | 736.10 | 4.040 | ||||||||||||||||
36 | LPS2 | Pumps | 8 | 0.11400 | 8760 | 24 | 10% | 1759.68 | 4.828 | ||||||||||||||||
37 | LDARREF | Flanges | 55 | 3.10E-07 | 8760 | 24 | 0% | 0.33 | 0.001 | ||||||||||||||||
38 | LDARREF | Valves | 9 | 7.80E-06 | 8760 | 24 | 0% | 1.35 | 0.004 | ||||||||||||||||
39 | LDARREF | Pumps | 2 | 2.40E-05 | 8760 | 24 | 0% | 0.93 | 0.003 | ||||||||||||||||
40 | LDARLPSSULF | Flanges | 76 | 3.10E-07 | 8760 | 24 | 0% | 0.45 | 0.001 | ||||||||||||||||
41 | LDARLPSSULF | Valves | 15 | 7.80E-06 | 8760 | 24 | 0% | 2.26 | 0.006 | ||||||||||||||||
42 | LDARLPSSULF | Pumps | 2 | 2.40E-05 | 8760 | 24 | 0% | 0.93 | 0.003 | ||||||||||||||||
43 | Total | 30976.78 | 140.63 | ||||||||||||||||||||||
44 | |||||||||||||||||||||||||
45 | |||||||||||||||||||||||||
46 | |||||||||||||||||||||||||
47 | |||||||||||||||||||||||||
48 | |||||||||||||||||||||||||
49 | |||||||||||||||||||||||||
50 |
51 | |||||||||||||||||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
52 | |||||||||||||||||||||||||
53 | |||||||||||||||||||||||||
54 | |||||||||||||||||||||||||
55 | |||||||||||||||||||||||||
56 | |||||||||||||||||||||||||
57 | Table B-2b: Area Specific Component Equipment Leak TAC Emissions | ||||||||||||||||||||||||
58 | Annual TAC Emissions (lb/yr) | Daily TAC Emissions (lb/day) | |||||||||||||||||||||||
59 | 91-57-6 | 91-20-3 | 108-95-2 | 1319-77-3 | 71-43-2 | 100-41-4 | 98-82-8 | 108-88-3 | 110-54-3 | 1330-20-7 | 7783-06-4 | 91-57-6 | 91-20-3 | 108-95-2 | 1319-77-3 | 71-43-2 | 100-41-4 | 98-82-8 | 108-88-3 | 110-54-3 | 1330-20-7 | 7783-06-4 | |||
60 | Area/Emission Point | VOC Emissions (lb/yr) | VOC Emissions (lb/day) | 2-Methyl naphthalene | Naphthalene | Phenol | Cresols (mixture), including m-cresol, o-cresol, p-cresol | Benzene | Ethyl benzene | Isopropylbenzene (Cumene) | Toluene | Hexane | Xylene (mixture), including m-xylene, o-xylene, p-xylene | Hydrogen sulfide | 2-Methyl naphthalene | Naphthalene | Phenol | Cresols (mixture), including m-cresol, o-cresol, p-cresol | Benzene | Ethyl benzene | Isopropylbenzene (Cumene) | Toluene | Hexane | Xylene (mixture), including m-xylene, o-xylene, p-xylene | Hydrogen sulfide |
61 | Front | 793.98 | 2.18 | 2.27E+00 | 1.32E+00 | 0.00E+00 | 0.00E+00 | 1.84E-01 | 4.68E-01 | 9.69E-02 | 1.66E+00 | 2.74E-01 | 2.76E+00 | 1.35E-01 | 6.23E-03 | 3.62E-03 | 0.00E+00 | 0.00E+00 | 5.05E-04 | 1.28E-03 | 2.66E-04 | 4.55E-03 | 7.52E-04 | 7.58E-03 | 3.70E-04 |
62 | Jail | 1377.65 | 3.78 | 3.94E+00 | 2.29E+00 | 0.00E+00 | 0.00E+00 | 3.20E-01 | 8.11E-01 | 1.68E-01 | 2.88E+00 | 4.75E-01 | 4.79E+00 | 2.34E-01 | 1.08E-02 | 6.28E-03 | 0.00E+00 | 0.00E+00 | 8.77E-04 | 2.23E-03 | 4.61E-04 | 7.90E-03 | 1.30E-03 | 1.32E-02 | 6.43E-04 |
63 | BO | 899.14 | 2.47 | 2.57E+00 | 1.49E+00 | 0.00E+00 | 0.00E+00 | 2.09E-01 | 5.30E-01 | 1.10E-01 | 1.88E+00 | 3.10E-01 | 3.13E+00 | 1.53E-01 | 7.06E-03 | 4.10E-03 | 0.00E+00 | 0.00E+00 | 5.72E-04 | 1.45E-03 | 3.01E-04 | 5.16E-03 | 8.51E-04 | 8.59E-03 | 4.19E-04 |
64 | UO | 329.94 | 0.91 | 9.44E-01 | 5.48E-01 | 0.00E+00 | 0.00E+00 | 7.65E-02 | 1.94E-01 | 4.03E-02 | 6.90E-01 | 1.14E-01 | 1.15E+00 | 5.61E-02 | 2.59E-03 | 1.50E-03 | 0.00E+00 | 0.00E+00 | 2.10E-04 | 5.33E-04 | 1.10E-04 | 1.89E-03 | 3.12E-04 | 3.15E-03 | 1.54E-04 |
65 | IT | 1559.02 | 4.28 | 4.46E+00 | 2.59E+00 | 0.00E+00 | 0.00E+00 | 3.62E-01 | 9.18E-01 | 1.90E-01 | 3.26E+00 | 5.38E-01 | 5.43E+00 | 2.65E-01 | 1.22E-02 | 7.10E-03 | 0.00E+00 | 0.00E+00 | 9.92E-04 | 2.52E-03 | 5.22E-04 | 8.94E-03 | 1.48E-03 | 1.49E-02 | 7.27E-04 |
66 | REF | 2209.25 | 6.06 | 6.32E+00 | 3.67E+00 | 0.00E+00 | 0.00E+00 | 5.13E-01 | 1.30E+00 | 2.70E-01 | 4.62E+00 | 7.62E-01 | 7.69E+00 | 3.76E-01 | 1.73E-02 | 1.01E-02 | 0.00E+00 | 0.00E+00 | 1.41E-03 | 3.57E-03 | 7.40E-04 | 1.27E-02 | 2.09E-03 | 2.11E-02 | 1.03E-03 |
67 | SULF | 1769.33 | 4.85 | 5.06E+00 | 2.94E+00 | 0.00E+00 | 0.00E+00 | 4.10E-01 | 1.04E+00 | 2.16E-01 | 3.70E+00 | 6.10E-01 | 6.16E+00 | 3.01E-01 | 1.39E-02 | 8.06E-03 | 0.00E+00 | 0.00E+00 | 1.13E-03 | 2.86E-03 | 5.92E-04 | 1.01E-02 | 1.67E-03 | 1.69E-02 | 8.25E-04 |
68 | LPS1 | 19476.15 | 106.88 | 5.57E+01 | 3.23E+01 | 0.00E+00 | 0.00E+00 | 4.52E+00 | 1.15E+01 | 2.38E+00 | 4.07E+01 | 6.72E+00 | 6.78E+01 | 3.31E+00 | 3.06E-01 | 1.77E-01 | 0.00E+00 | 0.00E+00 | 2.48E-02 | 6.30E-02 | 1.30E-02 | 2.23E-01 | 3.69E-02 | 3.72E-01 | 1.82E-02 |
69 | LPS2 | 2556.08 | 9.20 | 7.31E+00 | 4.24E+00 | 0.00E+00 | 0.00E+00 | 5.93E-01 | 1.51E+00 | 3.12E-01 | 5.34E+00 | 8.82E-01 | 8.90E+00 | 4.35E-01 | 2.63E-02 | 1.53E-02 | 0.00E+00 | 0.00E+00 | 2.13E-03 | 5.42E-03 | 1.12E-03 | 1.92E-02 | 3.17E-03 | 3.20E-02 | 1.56E-03 |
70 | LDARREF | 2.61 | 0.01 | 7.46E-03 | 4.33E-03 | 0.00E+00 | 0.00E+00 | 6.05E-04 | 1.54E-03 | 3.18E-04 | 5.45E-03 | 9.00E-04 | 9.08E-03 | 4.44E-04 | 2.05E-05 | 1.19E-05 | 0.00E+00 | 0.00E+00 | 1.66E-06 | 4.22E-06 | 8.74E-07 | 1.50E-05 | 2.47E-06 | 2.49E-05 | 1.22E-06 |
71 | LDARLPSSULF | 3.64 | 0.01 | 1.04E-02 | 6.04E-03 | 0.00E+00 | 0.00E+00 | 8.44E-04 | 2.14E-03 | 4.44E-04 | 7.60E-03 | 1.26E-03 | 1.27E-02 | 6.18E-04 | 2.86E-05 | 1.66E-05 | 0.00E+00 | 0.00E+00 | 2.32E-06 | 5.88E-06 | 1.22E-06 | 2.09E-05 | 3.44E-06 | 3.47E-05 | 1.70E-06 |
72 | Totals for TEU ID: FUG-1 | 8.86E+01 | 5.14E+01 | 0.00E+00 | 0.00E+00 | 7.19E+00 | 1.82E+01 | 3.78E+00 | 6.47E+01 | 1.07E+01 | 1.08E+02 | 5.27E+00 | 4.02E-01 | 2.33E-01 | 0.00E+00 | 0.00E+00 | 3.26E-02 | 8.28E-02 | 1.72E-02 | 2.94E-01 | 4.85E-02 | 4.89E-01 | 2.39E-02 | ||
73 | |||||||||||||||||||||||||
74 | 3.58E+02 |
A | B | C | D | E | F | G | H | I | J | K | L | M | N | |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
1 | Attachment B - Emission Calculations | |||||||||||||
2 | Table B-3: Summary of Compostional Analysis | |||||||||||||
4 | PPM by Weight | Wt. % | ||||||||||||
5 | Analyte | Base Oil | VGO | Wastewater | Used Motor Oil | Flux | Light Ends | Base Oil | VGO | Wastewater | Used Motor Oil | Flux | Composite of Non-distillate | Light Ends / Distillate |
6 | Diethanolamine | ND | ND | ND | ND | ND | ND | 0 | 0 | 0 | 0 | 0 | 0 | 0 |
7 | Triethylamine | ND | ND | ND | ND | ND | ND | 0 | 0 | 0 | 0 | 0 | 0 | 0 |
8 | 2-Chloronaphthalene | ND | ND | ND | ND | ND | ND | 0 | 0 | 0 | 0 | 0 | 0 | 0 |
9 | 2-Methyl naphthalene | ND | ND | ND | ND | ND | 2860 | 0 | 0 | 0 | 0 | 0 | 0 | 0.2860% |
10 | Acenaphthene | ND | ND | ND | ND | ND | ND | 0 | 0 | 0 | 0 | 0 | 0 | 0 |
11 | Acenaphthylene | ND | ND | ND | ND | ND | ND | 0 | 0 | 0 | 0 | 0 | 0 | 0 |
12 | Anthracene | ND | ND | ND | ND | ND | ND | 0 | 0 | 0 | 0 | 0 | 0 | 0 |
13 | Benzo(a)anthracene | ND | ND | ND | ND | ND | ND | 0 | 0 | 0 | 0 | 0 | 0 | 0 |
14 | Benzo(a)pyrene | ND | ND | ND | ND | ND | ND | 0 | 0 | 0 | 0 | 0 | 0 | 0 |
15 | Benzo(g,h,i)perylene | ND | ND | ND | ND | ND | ND | 0 | 0 | 0 | 0 | 0 | 0 | 0 |
16 | Benzo(k)fluoranthene | ND | ND | ND | ND | ND | ND | 0 | 0 | 0 | 0 | 0 | 0 | 0 |
17 | Benzo(b)fluoranthene | ND | ND | ND | ND | ND | ND | 0 | 0 | 0 | 0 | 0 | 0 | 0 |
18 | Chrysene | ND | ND | ND | ND | ND | ND | 0 | 0 | 0 | 0 | 0 | 0 | 0 |
19 | Dibenzo (a,h) anthracene | ND | ND | ND | ND | ND | ND | 0 | 0 | 0 | 0 | 0 | 0 | 0 |
20 | Fluoranthene | ND | ND | ND | ND | ND | ND | 0 | 0 | 0 | 0 | 0 | 0 | 0 |
21 | Fluorene | ND | ND | ND | ND | ND | ND | 0 | 0 | 0 | 0 | 0 | 0 | 0 |
22 | Indeno(1,2,3-cd)pyrene | ND | ND | ND | ND | ND | ND | 0 | 0 | 0 | 0 | 0 | 0 | 0 |
23 | Naphthalene | ND | ND | ND | ND | ND | 1660 | 0 | 0 | 0 | 0 | 0 | 0 | 0.1660% |
24 | Phenanthrene | ND | ND | ND | ND | ND | ND | 0 | 0 | 0 | 0 | 0 | 0 | 0 |
25 | Phenol | ND | ND | 34.9 | ND | ND | ND | 0 | 0 | 0.0035% | 0 | 0 | 0.0035% | 0 |
26 | Pyrene | ND | ND | ND | ND | ND | ND | 0 | 0 | 0 | 0 | 0 | 0 | 0 |
27 | Cresols (mixture), including m-cresol, o-cresol, p-cresol | ND | ND | 13 | ND | ND | ND | 0 | 0 | 0.0013% | 0 | 0 | 0.0013% | 0 |
28 | o-Cresol | ND | ND | ND | ND | ND | ND | 0 | 0 | 0 | 0 | 0 | 0 | 0 |
29 | Cresols, Total | ND | ND | ND | ND | ND | ND | 0 | 0 | 0 | 0 | 0 | 0 | 0 |
30 | 1,1´-Biphenyl | ND | ND | ND | ND | ND | ND | 0 | 0 | 0 | 0 | 0 | 0 | 0 |
31 | 3-Methylcholanthrene | ND | ND | ND | ND | ND | ND | 0 | 0 | 0 | 0 | 0 | 0 | 0 |
32 | 7,12-Dimethylbenz(a)anthracene | ND | ND | ND | ND | ND | ND | 0 | 0 | 0 | 0 | 0 | 0 | 0 |
33 | Benzo(e)pyrene | ND | ND | ND | ND | ND | ND | 0 | 0 | 0 | 0 | 0 | 0 | 0 |
34 | Perylene | ND | ND | ND | ND | ND | ND | 0 | 0 | 0 | 0 | 0 | 0 | 0 |
35 | Benzene | ND | ND | ND | 38.6 | ND | 232 | 0 | 0 | 0 | 0.0039% | 0 | 0.0039% | 0.0232% |
36 | Ethyl benzene | ND | ND | ND | 148 | ND | 589 | 0 | 0 | 0 | 0.0148% | 0 | 0.0148% | 0.0589% |
37 | Isopropylbenzene (Cumene) | ND | ND | ND | ND | ND | 122 | 0 | 0 | 0 | 0 | 0 | 0 | 0.0122% |
38 | m,p-Xylene | ND | ND | ND | 564 | ND | 2500 | 0 | 0 | 0 | 0.0564% | 0 | 0.0564% | 0.2500% |
39 | o-Xylene | ND | ND | ND | 251 | ND | 1360 | 0 | 0 | 0 | 0.0251% | 0 | 0.0251% | 0.1360% |
40 | Styrene | ND | ND | ND | ND | ND | ND | 0 | 0 | 0 | 0 | 0 | 0 | 0 |
41 | Toluene | ND | ND | ND | 508 | ND | 2090 | 0 | 0 | 0 | 0.0508% | 0 | 0.0508% | 0.2090% |
42 | 1,3-Butadiene | ND | ND | ND | ND | ND | ND | 0 | 0 | 0 | 0 | 0 | 0 | 0 |
43 | Hexane | ND | ND | ND | 57 | ND | 345 | 0 | 0 | 0 | 0.0057% | 0 | 0.0057% | 0.0345% |
44 | MIBK | ND | ND | ND | ND | ND | ND | 0 | 0 | 0 | 0 | 0 | 0 | 0 |
45 | Xylene (mixture), including m-xylene, o-xylene, p-xylene | ND | ND | ND | 815 | ND | 3480 | 0 | 0 | 0 | 0.0815% | 0 | 0.0815% | 0.3480% |
46 | 2,2,4-Trimethylpentane | ND | ND | ND | ND | ND | ND | 0 | 0 | 0 | 0 | 0 | 0 | 0 |
47 | Hydrogen sulfide | ND | ND | ND | ND | ND | 170 | 0 | 0 | 0 | 0 | 0 | 0 | 0.0170% |
49 | Note: The analytical report identified the analyte "m7p-cresol" as being detected in the wastewater sample at 13 mg/l. This analyte was renamed above to "Cresols (mixture), including m-cresol, o-cresol, p-cresol" to align with CAO nomenclature. | |||||||||||||
50 | Analytical report name of isopropylbenzene changed to Isopropylbenzene (Cumene) | |||||||||||||
52 | Tank Vapor Speciation using AP-42 Methodology | |||||||||||||
53 | Worse-case Liquid Composition | Distillate Tanks | All Other Tanks |
54 | Analyte | CAS # | Annual | Short-term | Annual | Short-term | ||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
55 | 2-Methyl naphthalene | 91-57-6 | 0.286000% | 0.00031% | 0.00063% | 0% | 0% | |||||||
56 | Naphthalene | 91-20-3 | 0.166000% | 0.00072% | 0.0013% | 0% | 0% | |||||||
57 | Phenol | 108-95-2 | 0.000000% | 0% | 0% | 0.000018% | 0.000038% | |||||||
58 | Cresols (mixture), including m-cresol, o-cresol, p-cresol | 1319-77-3 | 0.000000% | 0% | 0% | 0.000004% | 0.000009% | |||||||
59 | Benzene | 71-43-2 | 0.023200% | 0.043% | 0.050% | 0.0067% | 0.0077% | |||||||
60 | Ethyl benzene | 100-41-4 | 0.058900% | 0.010% | 0.014% | 0.0024% | 0.0033% | |||||||
61 | Isopropylbenzene (Cumene) | 98-82-8 | 0.012200% | 0.0010% | 0.0015% | 0% | 0% | |||||||
62 | Toluene | 108-88-3 | 0.209000% | 0.11% | 0.14% | 0.026% | 0.032% | |||||||
63 | Hexane | 110-54-3 | 0.034500% | 0.10% | 0.11% | 0.016% | 0.018% | |||||||
64 | Xylene (mixture), including m-xylene, o-xylene, p-xylene | 1330-20-7 | 0.348000% | 0.053% | 0.073% | 0.012% | 0.016% | |||||||
65 | Hydrogen sulfide | 7783-06-4 | 0.017000% | 6.62% | 4.75% | 0% | 0% |
A | B | C | D | E | F | G | H | I | J | K | L | M | N | O | P | Q | R | S | T | U | V | W | X | Y | Z | AA | AB | AC | AD | AE | AF | AG | AH | AI | AJ | AK | AL | AM | AN | AO | AP | AQ | AR | AS | AT | AU | AV | AW | AX | AY | AZ | BA | BB | BC | BD | BE | BF | BG | BH | |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
1 | Ecolube Recovery | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
2 | Distillate Vapor Speciation Calculation | January | February | March | April | May | June | July | August | September | October | November | December | Annual | Max of 95 F | |||||||||||||||||||||||||||||||||||||||||||||
3 | Solution Composition | 501.40 | 503.45 | 506.65 | 510.10 | 516.30 | 521.15 | 528.05 | 527.50 | 522.95 | 513.25 | 505.50 | 500.85 | 554.67 | ||||||||||||||||||||||||||||||||||||||||||||||
4 | Component | Weight % in Liquid Phase |
MW (lb/lb-mole) |
No. Moles |
Mole % in Liquid Phase |
Liquid Mole Fraction (Xi) (1) | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase | Max of any month | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase | |
5 | 00091-57-6 | 2-Methyl naphthalene | 0.2860% | 142.20 | 0.0000201 | 0.29% | 0.00 | 4.28E-06 | 0.00 | 0.000 | 0.000% | 4.80E-06 | 0.00 | 0.000 | 0.000% | 5.74E-06 | 0.00 | 0.000 | 0.000% | 6.92E-06 | 0.00 | 0.000 | 0.000% | 9.63E-06 | 0.00 | 0.000 | 0.000% | 1.24E-05 | 0.00 | 0.000 | 0.000% | 1.75E-05 | 2.29E-06 | 3.26E-04 | 0.000% | 1.70E-05 | 2.26E-06 | 3.21E-04 | 0.000% | 1.36E-05 | 1.97E-06 | 2.80E-04 | 0.000% | 8.20E-06 | 1.45E-06 | 2.06E-04 | 0.000% | 5.38E-06 | 1.12E-06 | 1.59E-04 | 0.000% | 4.15E-06 | 9.54E-07 | 1.36E-04 | 0.000% | 0.000% | 5.97E-05 | 4.74E-06 | 6.74E-04 | 0.001% |
6 | 00091-20-3 | Naphthalene | 0.1660% | 128.17 | 0.0000130 | 0.19% | 0.00 | 1.30E-05 | 0.00 | 0.000 | 0.000% | 1.44E-05 | 0.00 | 0.000 | 0.000% | 1.69E-05 | 0.00 | 0.000 | 0.000% | 1.99E-05 | 0.00 | 0.000 | 0.000% | 2.66E-05 | 0.00 | 0.001 | 0.001% | 3.32E-05 | 0.00 | 0.001 | 0.001% | 4.50E-05 | 5.90E-06 | 7.57E-04 | 0.001% | 4.40E-05 | 5.83E-06 | 7.47E-04 | 0.001% | 3.60E-05 | 5.22E-06 | 6.69E-04 | 0.001% | 2.31E-05 | 4.08E-06 | 5.23E-04 | 0.001% | 1.60E-05 | 3.32E-06 | 4.26E-04 | 0.000% | 1.27E-05 | 2.92E-06 | 3.74E-04 | 0.000% | 0.001% | 1.34E-04 | 1.06E-05 | 1.36E-03 | 0.001% |
7 | 00108-95-2 | Phenol | 0% | 94.11 | 0.0000000 | 0.00% | 0.00 | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% |
8 | 00095-48-7 | Cresols (mixture), including m-cresol, o-cresol, p-cresol | 0% | 108.14 | 0.0000000 | 0.00% | 0.00 | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% |
9 | 00071-43-2 | Benzene | 0.0232% | 78.11 | 0.0000030 | 0.04% | 0.00 | 2.06E-03 | 0.00 | 0.037 | 0.036% | 2.19E-03 | 0.00 | 0.037 | 0.036% | 2.41E-03 | 0.00 | 0.038 | 0.037% | 2.67E-03 | 0.00 | 0.039 | 0.038% | 3.18E-03 | 0.00 | 0.041 | 0.040% | 3.64E-03 | 0.00 | 0.043 | 0.041% | 4.39E-03 | 5.76E-04 | 4.50E-02 | 0.043% | 4.33E-03 | 5.74E-04 | 4.48E-02 | 0.043% | 3.83E-03 | 5.55E-04 | 4.34E-02 | 0.041% | 2.92E-03 | 5.16E-04 | 4.03E-02 | 0.039% | 2.33E-03 | 4.85E-04 | 3.79E-02 | 0.037% | 2.03E-03 | 4.66E-04 | 3.64E-02 | 0.035% | 0.043% | 8.58E-03 | 6.81E-04 | 5.32E-02 | 0.050% |
10 | 00100-41-4 | Ethyl benzene | 0.0589% | 106.17 | 0.0000055 | 0.08% | 0.00 | 2.97E-04 | 0.00 | 0.007 | 0.007% | 3.21E-04 | 0.00 | 0.007 | 0.007% | 3.62E-04 | 0.00 | 0.008 | 0.008% | 4.11E-04 | 0.00 | 0.008 | 0.008% | 5.14E-04 | 0.00 | 0.009 | 0.009% | 6.09E-04 | 0.00 | 0.010 | 0.009% | 7.71E-04 | 1.01E-04 | 1.07E-02 | 0.010% | 7.57E-04 | 1.00E-04 | 1.06E-02 | 0.010% | 6.48E-04 | 9.41E-05 | 9.99E-03 | 0.010% | 4.61E-04 | 8.15E-05 | 8.66E-03 | 0.008% | 3.47E-04 | 7.22E-05 | 7.67E-03 | 0.007% | 2.91E-04 | 6.69E-05 | 7.11E-03 | 0.007% | 0.010% | 1.78E-03 | 1.42E-04 | 1.50E-02 | 0.014% |
11 | 00098-82-8 | Isopropylbenzene (Cumene) | 0.0122% | 120.19 | 0.0000010 | 0.01% | 0.00 | 2.38E-05 | 0.00 | 0.001 | 0.001% | 2.59E-05 | 0.00 | 0.001 | 0.001% | 2.95E-05 | 0.00 | 0.001 | 0.001% | 3.38E-05 | 0.00 | 0.001 | 0.001% | 4.30E-05 | 0.00 | 0.001 | 0.001% | 5.16E-05 | 0.00 | 0.001 | 0.001% | 6.65E-05 | 8.72E-06 | 1.05E-03 | 0.001% | 6.52E-05 | 8.64E-06 | 1.04E-03 | 0.001% | 5.52E-05 | 8.01E-06 | 9.63E-04 | 0.001% | 3.83E-05 | 6.76E-06 | 8.13E-04 | 0.001% | 2.82E-05 | 5.86E-06 | 7.04E-04 | 0.001% | 2.33E-05 | 5.36E-06 | 6.44E-04 | 0.001% | 0.001% | 1.64E-04 | 1.30E-05 | 1.56E-03 | 0.001% |
12 | 00108-88-3 | Toluene | 0.2090% | 92.14 | 0.0000227 | 0.33% | 0.00 | 4.18E-03 | 0.00 | 0.087 | 0.085% | 4.47E-03 | 0.00 | 0.090 | 0.087% | 4.98E-03 | 0.00 | 0.093 | 0.090% | 5.57E-03 | 0.00 | 0.097 | 0.093% | 6.80E-03 | 0.00 | 0.104 | 0.100% | 7.91E-03 | 0.00 | 0.110 | 0.105% | 9.75E-03 | 1.28E-03 | 1.18E-01 | 0.112% | 9.59E-03 | 1.27E-03 | 1.17E-01 | 0.111% | 8.36E-03 | 1.21E-03 | 1.12E-01 | 0.106% | 6.17E-03 | 1.09E-03 | 1.01E-01 | 0.097% | 4.79E-03 | 9.97E-04 | 9.19E-02 | 0.089% | 4.10E-03 | 9.43E-04 | 8.69E-02 | 0.084% | 0.112% | 2.06E-02 | 1.64E-03 | 1.51E-01 | 0.141% |
13 | 00110-54-3 | Hexane | 0.0345% | 86.18 | 0.0000040 | 0.06% | 0.00 | 4.69E-03 | 0.00 | 0.092 | 0.089% | 4.97E-03 | 0.00 | 0.093 | 0.090% | 5.43E-03 | 0.00 | 0.095 | 0.092% | 5.97E-03 | 0.00 | 0.097 | 0.094% | 7.05E-03 | 0.00 | 0.101 | 0.097% | 8.00E-03 | 0.00 | 0.104 | 0.099% | 9.54E-03 | 1.25E-03 | 1.08E-01 | 0.102% | 9.41E-03 | 1.25E-03 | 1.07E-01 | 0.102% | 8.38E-03 | 1.22E-03 | 1.05E-01 | 0.100% | 6.50E-03 | 1.15E-03 | 9.90E-02 | 0.095% | 5.26E-03 | 1.09E-03 | 9.43E-02 | 0.091% | 4.61E-03 | 1.06E-03 | 9.15E-02 | 0.089% | 0.102% | 1.79E-02 | 1.42E-03 | 1.22E-01 | 0.114% |
14 | 00108-38-3 | Xylene (mixture), including m-xylene, o-xylene, p-xylene | 0.3480% | 106.17 | 0.0000328 | 0.48% | 0.00 | 1.52E-03 | 0.00 | 0.037 | 0.036% | 1.65E-03 | 0.00 | 0.038 | 0.037% | 1.86E-03 | 0.00 | 0.040 | 0.039% | 2.11E-03 | 0.00 | 0.042 | 0.041% | 2.64E-03 | 0.00 | 0.047 | 0.045% | 3.14E-03 | 0.00 | 0.050 | 0.048% | 3.98E-03 | 5.21E-04 | 5.53E-02 | 0.053% | 3.90E-03 | 5.17E-04 | 5.49E-02 | 0.052% | 3.34E-03 | 4.85E-04 | 5.14E-02 | 0.049% | 2.37E-03 | 4.19E-04 | 4.45E-02 | 0.043% | 1.78E-03 | 3.70E-04 | 3.93E-02 | 0.038% | 1.49E-03 | 3.43E-04 | 3.64E-02 | 0.035% | 0.053% | 9.27E-03 | 7.36E-04 | 7.81E-02 | 0.073% |
15 | 07783-06-4 | Hydrogen sulfide | 0.0170% | 34.08 | 0.0000050 | 0.0728% | 0.0007 | 8.77E-01 | 0.19927 | 6.792 | 6.598% | 9.06E-01 | 0.20 | 6.712 | 6.508% | 9.52E-01 | 0.19 | 6.590 | 6.371% | 1.00E+00 | 0.19 | 6.462 | 6.227% | 1.10E+00 | 0.18 | 6.242 | 5.982% | 1.19E+00 | 0.18 | 6.077 | 5.800% | 1.31E+00 | 1.72E-01 | 5.85E+00 | 5.556% | 1.30E+00 | 1.72E-01 | 5.87E+00 | 5.575% | 1.22E+00 | 1.77E-01 | 6.02E+00 | 5.735% | 1.05E+00 | 1.86E-01 | 6.35E+00 | 6.101% | 9.35E-01 | 1.95E-01 | 6.63E+00 | 6.419% | 8.69E-01 | 2.00E-01 | 6.81E+00 | 6.623% | 6.623% | 1.88E+00 | 1.49E-01 | 5.09E+00 | 4.747% |
16 | Oil (Fuel oil No. 2 basis) | 49.4226% | 188.00 | 0.0026289 | 38.35% | 0.38 | 9.18E-03 | 0.00 | 0.392 | 0.381% | 9.87E-03 | 0.00 | 0.403 | 0.391% | 1.10E-02 | 0.00 | 0.421 | 0.407% | 1.24E-02 | 0.00 | 0.441 | 0.425% | 1.53E-02 | 0.00 | 0.478 | 0.459% | 1.80E-02 | 0.00 | 0.509 | 0.486% | 2.25E-02 | 2.95E-03 | 5.55E-01 | 0.526% | 2.21E-02 | 2.93E-03 | 5.51E-01 | 0.523% | 1.91E-02 | 2.77E-03 | 5.21E-01 | 0.496% | 1.38E-02 | 2.45E-03 | 4.60E-01 | 0.442% | 1.06E-02 | 2.21E-03 | 4.15E-01 | 0.401% | 9.00E-03 | 2.07E-03 | 3.89E-01 | 0.378% | 0.526% | 5.06E-02 | 4.01E-03 | 7.55E-01 | 0.703% | |
17 | Oil (JP-4 basis) | 49.4226% | 120.00 | 0.0041186 | 60.09% | 0.60 | 3.50E+00 | 0.80 | 95.489 | 92.768% | 3.67E+00 | 0.80 | 95.755 | 92.843% | 3.95E+00 | 0.80 | 96.160 | 92.956% | 4.26E+00 | 0.80 | 96.584 | 93.072% | 4.88E+00 | 0.81 | 97.314 | 93.268% | 5.42E+00 | 0.82 | 97.858 | 93.410% | 6.27E+00 | 8.22E-01 | 9.86E+01 | 93.596% | 6.20E+00 | 8.21E-01 | 9.85E+01 | 93.582% | 5.63E+00 | 8.17E-01 | 9.81E+01 | 93.461% | 4.57E+00 | 8.08E-01 | 9.70E+01 | 93.174% | 3.84E+00 | 8.00E-01 | 9.60E+01 | 92.916% | 3.46E+00 | 7.95E-01 | 9.54E+01 | 92.747% | 93.596% | 1.06E+01 | 8.42E-01 | 1.01E+02 | 94.155% | |
18 | 1404.66 | 0.0068545 | 100% | 1.00 | 4.40E+00 | 1.00 | 102.93 | 100% | 4.60E+00 | 1.00 | 103.14 | 100% | 4.92E+00 | 1.00 | 103.45 | 100% | 5.30E+00 | 1.00 | 103.77 | 100% | 6.02E+00 | 1.00 | 104.34 | 100% | 6.65E+00 | 1.00 | 104.76 | 100% | 7.63E+00 | 1.00 | 105.34 | 100% | 7.55E+00 | 1.00 | 105.29 | 100% | 6.89E+00 | 1.00 | 104.91 | 100% | 5.66E+00 | 1.00 | 104.06 | 100% | 4.80E+00 | 1.00 | 103.34 | 100% | 4.35E+00 | 1.00 | 102.88 | 100% | 101.1% | 1.26E+01 | 1.00 | 107.30 | 100% | |||
19 | assume xylene is m-xylene, lowest boiling point | 0.638 | psi | 0.667 | psi | 0.714 | psi | 0.768 | psi | 0.874 | psi | 0.964 | psi | 1.106 | psi | 1.094 | psi | 1.000 | psi | 0.820 | psi | 0.697 | psi | 0.631 | psi | 1.826 | psi | |||||||||||||||||||||||||||||||||
20 | assume cresols are o-cresol, lowest boiling point | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
21 | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
22 | 95 F Max | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
23 | Solution Conditions | R | 501.40 | 503.45 | 506.65 | 510.10 | 516.30 | 521.15 | 528.05 | 527.50 | 522.95 | 513.25 | 505.50 | 500.85 | 554.67 | |||||||||||||||||||||||||||||||||||||||||||||
24 | Solution Temperature | ºC | 5.41 | 6.54 | 8.32 | 10.24 | 13.68 | 16.38 | 20.21 | 19.91 | 17.38 | 11.99 | 7.68 | 5.10 | 35.00 | |||||||||||||||||||||||||||||||||||||||||||||
25 | Atmospheric Pressure | psi | 0.638 | 0.667 | 0.714 | 0.768 | 0.874 | 0.964 | 1.106 | 1.094 | 1.000 | 0.820 | 0.697 | 0.631 | psi | |||||||||||||||||||||||||||||||||||||||||||||
26 | Vapor Molecular Weight | Mv | 102.93 | 103.14 | 103.45 | 103.77 | 104.34 | 104.76 | 105.34 | 105.29 | 104.91 | 104.06 | 103.34 | 102.88 | 1.00 | |||||||||||||||||||||||||||||||||||||||||||||
27 | Pure Vapor Pressure Calculation | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
28 | Component | Antoine's Coefficients (1) | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
29 | A | B | C | kPa | kPa | kPa | kPa | kPa | kPa | kPa | kPa | kPa | kPa | kPa | kPa | kPa | ||||||||||||||||||||||||||||||||||||||||||||
30 | 00091-57-6 | 2-Methyl naphthalene | 4.19 | 1840.27 | -74.76 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.01 | 0.01 | 0.00 | 0.00 | 0.00 | 0.00 | 0.02 | ||||||||||||||||||||||||||||||||||||||||||
31 | 00091-20-3 | Naphthalene | 7.15 | 1831.60 | 211.82 | 0.01 | 0.01 | 0.01 | 0.01 | 0.01 | 0.02 | 0.02 | 0.02 | 0.02 | 0.01 | 0.01 | 0.01 | 0.07 | ||||||||||||||||||||||||||||||||||||||||||
32 | 00108-95-2 | Phenol | 7.12 | 1509.70 | 174.20 | 0.01 | 0.01 | 0.01 | 0.01 | 0.02 | 0.02 | 0.03 | 0.03 | 0.02 | 0.01 | 0.01 | 0.01 | 0.11 | ||||||||||||||||||||||||||||||||||||||||||
33 | 00095-48-7 | Cresols (mixture), including m-cresol, o-cresol, p-cresol | 6.84 | 1391.30 | 160.18 | 0.00 | 0.00 | 0.01 | 0.01 | 0.01 | 0.01 | 0.02 | 0.02 | 0.01 | 0.01 | 0.00 | 0.00 | 0.07 | ||||||||||||||||||||||||||||||||||||||||||
34 | 00071-43-2 | Benzene | 6.91 | 1211.00 | 220.79 | 4.75 | 5.06 | 5.56 | 6.15 | 7.35 | 8.41 | 10.14 | 9.99 | 8.84 | 6.74 | 5.38 | 4.68 | 19.79 | ||||||||||||||||||||||||||||||||||||||||||
35 | 00100-41-4 | Ethyl benzene | 6.95 | 1419.30 | 212.61 | 0.37 | 0.40 | 0.45 | 0.51 | 0.64 | 0.75 | 0.95 | 0.93 | 0.80 | 0.57 | 0.43 | 0.36 | 2.20 | ||||||||||||||||||||||||||||||||||||||||||
36 | 00098-82-8 | Isopropylbenzene (Cumene) | 6.93 | 1455.80 | 207.20 | 0.16 | 0.17 | 0.20 | 0.23 | 0.29 | 0.35 | 0.45 | 0.44 | 0.37 | 0.26 | 0.19 | 0.16 | 1.10 | ||||||||||||||||||||||||||||||||||||||||||
37 | 00108-88-3 | Toluene | 7.02 | 1377.60 | 222.64 | 1.26 | 1.35 | 1.50 | 1.68 | 2.05 | 2.39 | 2.95 | 2.90 | 2.53 | 1.86 | 1.45 | 1.24 | 6.24 | ||||||||||||||||||||||||||||||||||||||||||
38 | 00110-54-3 | Hexane | 6.88 | 1171.50 | 224.37 | 8.03 | 8.50 | 9.30 | 10.22 | 12.07 | 13.70 | 16.33 | 16.11 | 14.35 | 11.13 | 9.01 | 7.90 | 30.63 | ||||||||||||||||||||||||||||||||||||||||||
39 | 00108-38-3 | Xylene (mixture), including m-xylene, o-xylene, p-xylene | 7.01 | 1462.30 | 215.11 | 0.32 | 0.34 | 0.39 | 0.44 | 0.55 | 0.66 | 0.83 | 0.82 | 0.70 | 0.50 | 0.37 | 0.31 | 1.94 | ||||||||||||||||||||||||||||||||||||||||||
40 | 07783-06-4 | Hydrogen sulfide | 4.53 | 958.59 | -0.54 | 1,204.82 | 1,244.48 | 1,308.33 | 1,379.87 | 1,515.70 | 1,628.66 | 1,799.93 | 1,785.81 | 1,672.13 | 1,447.70 | 1,285.11 | 1,194.34 | 2,586.06 | ||||||||||||||||||||||||||||||||||||||||||
41 | Oil (Fuel oil No. 2 basis) | 12.10 | 8907.00 | 0.02393 | 0.02573 | 0.02877 | 0.03240 | 0.03996 | 0.04692 | 0.05866 | 0.05764 | 0.04976 | 0.03607 | 0.02764 | 0.02347 | 0.13180 | ||||||||||||||||||||||||||||||||||||||||||||
42 | Oil (JP-4 basis) | 11.37 | 5,784.30 | 5.82675 | 6.10699 | 6.56663 | 7.09377 | 8.12859 | 9.02186 | 10.42995 | 10.31150 | 9.37319 | 7.60504 | 6.39827 | 5.75340 | 17.64399 | ||||||||||||||||||||||||||||||||||||||||||||
43 | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
44 |
(1) Antoine's Coefficients for EG, PH and ET are from AP-42,
Section 7.1, Organic Liquid Storage Tanks, June 2020, Table 7.1-3;
Antoine's equation is log Piº = A - B/(T+C), where T is in ºC and Piº is in mmHg. Antoine's equation is ln Piº = A + B/(T+C), where T is in K and Piº is in kPa. |
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45 | K, bar | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
46 | (10^(A-(B/(T+C))))*0.13332239 | C, mmHg | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
47 | EXP(A+(B/(T+273.15+C))) | K, kPa | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
48 | (exp(A-(B/(T))))*101.325/14.696 | R, psia | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
49 | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
50 |
51 | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
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52 | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
53 | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
54 | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
55 | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
56 | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
57 | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
58 | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
59 | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
60 | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
61 | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
62 | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
63 | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
64 | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
65 |
A | B | C | D | E | F | G | H | I | J | K | L | M | N | O | P | Q | R | S | T | U | V | W | X | Y | Z | AA | AB | AC | AD | AE | AF | AG | AH | AI | AJ | AK | AL | AM | AN | AO | AP | AQ | AR | AS | AT | AU | AV | AW | AX | AY | AZ | BA | BB | BC | BD | BE | BF | BG | BH | |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
1 | Ecolube Recovery | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
2 | Non-Distillate Vapor Speciation Calculation | January | February | March | April | May | June | July | August | September | October | November | December | Annual | Max of 95 F | |||||||||||||||||||||||||||||||||||||||||||||
3 | Solution Composition | 501.40 | 503.45 | 506.65 | 510.10 | 516.30 | 521.15 | 528.05 | 527.50 | 522.95 | 513.25 | 505.50 | 500.85 | 554.67 | ||||||||||||||||||||||||||||||||||||||||||||||
4 | Component | Weight % in Liquid Phase |
MW (lb/lb-mole) |
No. Moles |
Mole % in Liquid Phase |
Liquid Mole Fraction (Xi) (1) | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase | Max of any month | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase | |
5 | 00091-57-6 | 2-Methyl naphthalene | 0% | 142.20 | 0.0000000 | 0.00% | 0.00 | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% |
6 | 00091-20-3 | Naphthalene | 0% | 128.17 | 0.0000000 | 0.00% | 0.00 | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% |
7 | 00108-95-2 | Phenol | 0.0035% | 94.11 | 0.0000004 | 0.01% | 0.00 | 3.67E-07 | 0.00 | 0.000 | 0.000% | 4.15E-07 | 0.00 | 0.000 | 0.000% | 5.00E-07 | 0.00 | 0.000 | 0.000% | 6.10E-07 | 0.00 | 0.000 | 0.000% | 8.61E-07 | 0.00 | 0.000 | 0.000% | 1.12E-06 | 0.00 | 0.000 | 0.000% | 1.60E-06 | 2.31E-07 | 2.17E-05 | 0.000% | 1.56E-06 | 2.27E-07 | 2.13E-05 | 0.000% | 1.23E-06 | 1.97E-07 | 1.85E-05 | 0.000% | 7.28E-07 | 1.44E-07 | 1.35E-05 | 0.000% | 4.68E-07 | 1.10E-07 | 1.03E-05 | 0.000% | 3.55E-07 | 9.27E-08 | 8.73E-06 | 0.000% | 0.000% | 5.67E-06 | 4.82E-07 | 4.54E-05 | 0.000% |
8 | 00095-48-7 | Cresols (mixture), including m-cresol, o-cresol, p-cresol | 0.0013% | 108.14 | 0.0000001 | 0.00% | 0.00 | 6.31E-08 | 0.00 | 0.000 | 0.000% | 7.20E-08 | 0.00 | 0.000 | 0.000% | 8.82E-08 | 0.00 | 0.000 | 0.000% | 1.09E-07 | 0.00 | 0.000 | 0.000% | 1.58E-07 | 0.00 | 0.000 | 0.000% | 2.10E-07 | 0.00 | 0.000 | 0.000% | 3.09E-07 | 4.44E-08 | 4.80E-06 | 0.000% | 2.99E-07 | 4.36E-08 | 4.71E-06 | 0.000% | 2.32E-07 | 3.72E-08 | 4.03E-06 | 0.000% | 1.32E-07 | 2.61E-08 | 2.82E-06 | 0.000% | 8.20E-08 | 1.93E-08 | 2.08E-06 | 0.000% | 6.09E-08 | 1.59E-08 | 1.72E-06 | 0.000% | 0.000% | 1.19E-06 | 1.01E-07 | 1.09E-05 | 0.000% |
9 | 00071-43-2 | Benzene | 0.0039% | 78.11 | 0.0000005 | 0.01% | 0.00 | 3.35E-04 | 0.00 | 0.007 | 0.006% | 3.57E-04 | 0.00 | 0.007 | 0.006% | 3.92E-04 | 0.00 | 0.007 | 0.006% | 4.34E-04 | 0.00 | 0.007 | 0.006% | 5.18E-04 | 0.00 | 0.007 | 0.006% | 5.93E-04 | 0.00 | 0.008 | 0.006% | 7.15E-04 | 1.03E-04 | 8.04E-03 | 0.007% | 7.04E-04 | 1.03E-04 | 8.01E-03 | 0.007% | 6.23E-04 | 9.98E-05 | 7.79E-03 | 0.006% | 4.75E-04 | 9.38E-05 | 7.33E-03 | 0.006% | 3.79E-04 | 8.90E-05 | 6.95E-03 | 0.006% | 3.30E-04 | 8.61E-05 | 6.72E-03 | 0.006% | 0.007% | 1.40E-03 | 1.19E-04 | 9.26E-03 | 0.008% |
10 | 00100-41-4 | Ethyl benzene | 0.0148% | 106.17 | 0.0000014 | 0.02% | 0.00 | 7.30E-05 | 0.00 | 0.002 | 0.002% | 7.89E-05 | 0.00 | 0.002 | 0.002% | 8.90E-05 | 0.00 | 0.002 | 0.002% | 1.01E-04 | 0.00 | 0.002 | 0.002% | 1.26E-04 | 0.00 | 0.002 | 0.002% | 1.50E-04 | 0.00 | 0.003 | 0.002% | 1.89E-04 | 2.73E-05 | 2.89E-03 | 0.002% | 1.86E-04 | 2.71E-05 | 2.87E-03 | 0.002% | 1.59E-04 | 2.55E-05 | 2.71E-03 | 0.002% | 1.13E-04 | 2.24E-05 | 2.38E-03 | 0.002% | 8.52E-05 | 2.00E-05 | 2.12E-03 | 0.002% | 7.15E-05 | 1.87E-05 | 1.98E-03 | 0.002% | 0.002% | 4.38E-04 | 3.72E-05 | 3.95E-03 | 0.003% |
11 | 00098-82-8 | Isopropylbenzene (Cumene) | 0% | 120.19 | 0.0000000 | 0.00% | 0.00 | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% |
12 | 00108-88-3 | Toluene | 0.0508% | 92.14 | 0.0000055 | 0.08% | 0.00 | 9.92E-04 | 0.00 | 0.024 | 0.020% | 1.06E-03 | 0.00 | 0.024 | 0.020% | 1.18E-03 | 0.00 | 0.025 | 0.021% | 1.32E-03 | 0.00 | 0.026 | 0.022% | 1.62E-03 | 0.00 | 0.027 | 0.023% | 1.88E-03 | 0.00 | 0.029 | 0.024% | 2.32E-03 | 3.33E-04 | 3.07E-02 | 0.026% | 2.28E-03 | 3.32E-04 | 3.06E-02 | 0.025% | 1.99E-03 | 3.18E-04 | 2.93E-02 | 0.024% | 1.47E-03 | 2.90E-04 | 2.67E-02 | 0.022% | 1.14E-03 | 2.67E-04 | 2.46E-02 | 0.021% | 9.74E-04 | 2.54E-04 | 2.34E-02 | 0.020% | 0.026% | 4.90E-03 | 4.17E-04 | 3.84E-02 | 0.032% |
13 | 00110-54-3 | Hexane | 0.0057% | 86.18 | 0.0000007 | 0.01% | 0.00 | 7.57E-04 | 0.00 | 0.017 | 0.014% | 8.02E-04 | 0.00 | 0.017 | 0.014% | 8.77E-04 | 0.00 | 0.017 | 0.014% | 9.64E-04 | 0.00 | 0.018 | 0.015% | 1.14E-03 | 0.00 | 0.018 | 0.015% | 1.29E-03 | 0.00 | 0.019 | 0.015% | 1.54E-03 | 2.22E-04 | 1.91E-02 | 0.016% | 1.52E-03 | 2.21E-04 | 1.91E-02 | 0.016% | 1.35E-03 | 2.17E-04 | 1.87E-02 | 0.016% | 1.05E-03 | 2.07E-04 | 1.79E-02 | 0.015% | 8.50E-04 | 1.99E-04 | 1.72E-02 | 0.014% | 7.45E-04 | 1.95E-04 | 1.68E-02 | 0.014% | 0.016% | 2.89E-03 | 2.46E-04 | 2.12E-02 | 0.018% |
14 | 00108-38-3 | Xylene (mixture), including m-xylene, o-xylene, p-xylene | 0.0815% | 106.17 | 0.0000077 | 0.11% | 0.00 | 3.48E-04 | 0.00 | 0.010 | 0.008% | 3.77E-04 | 0.00 | 0.010 | 0.008% | 4.25E-04 | 0.00 | 0.010 | 0.009% | 4.83E-04 | 0.00 | 0.011 | 0.009% | 6.05E-04 | 0.00 | 0.012 | 0.010% | 7.18E-04 | 0.00 | 0.013 | 0.011% | 9.11E-04 | 1.31E-04 | 1.39E-02 | 0.012% | 8.94E-04 | 1.30E-04 | 1.38E-02 | 0.011% | 7.65E-04 | 1.22E-04 | 1.30E-02 | 0.011% | 5.42E-04 | 1.07E-04 | 1.14E-02 | 0.009% | 4.07E-04 | 9.56E-05 | 1.02E-02 | 0.008% | 3.41E-04 | 8.91E-05 | 9.46E-03 | 0.008% | 0.012% | 2.12E-03 | 1.80E-04 | 1.91E-02 | 0.016% |
15 | 07783-06-4 | Hydrogen sulfide | 0% | 34.08 | 0.0000000 | 0.0000% | 0.0000 | 0.00E+00 | 0.00000 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% |
16 | Oil (Fuel oil No. 2 basis) | 44.0% | 188.00 | 0.0023404 | 33.39% | 0.33 | 7.99E-03 | 0.00 | 0.387 | 0.322% | 8.59E-03 | 0.00 | 0.397 | 0.331% | 9.61E-03 | 0.00 | 0.413 | 0.344% | 1.08E-02 | 0.00 | 0.431 | 0.358% | 1.33E-02 | 0.00 | 0.463 | 0.386% | 1.57E-02 | 0.00 | 0.490 | 0.408% | 1.96E-02 | 2.82E-03 | 5.30E-01 | 0.441% | 1.92E-02 | 2.80E-03 | 5.27E-01 | 0.438% | 1.66E-02 | 2.66E-03 | 5.00E-01 | 0.416% | 1.20E-02 | 2.38E-03 | 4.47E-01 | 0.372% | 9.23E-03 | 2.17E-03 | 4.07E-01 | 0.339% | 7.84E-03 | 2.05E-03 | 3.85E-01 | 0.320% | 0.441% | 4.40E-02 | 3.74E-03 | 7.03E-01 | 0.585% | |
17 | Oil (JP-4 basis) | 55.839% | 120.00 | 0.0046532 | 66.38% | 0.66 | 3.87E+00 | 1.00 | 119.675 | 99.629% | 4.05E+00 | 1.00 | 119.667 | 99.619% | 4.36E+00 | 1.00 | 119.655 | 99.605% | 4.71E+00 | 1.00 | 119.641 | 99.588% | 5.40E+00 | 1.00 | 119.615 | 99.558% | 5.99E+00 | 1.00 | 119.595 | 99.533% | 6.92E+00 | 9.96E-01 | 1.20E+02 | 99.497% | 6.84E+00 | 9.96E-01 | 1.20E+02 | 99.500% | 6.22E+00 | 9.97E-01 | 1.20E+02 | 99.524% | 5.05E+00 | 9.97E-01 | 1.20E+02 | 99.573% | 4.25E+00 | 9.97E-01 | 1.20E+02 | 99.610% | 3.82E+00 | 9.97E-01 | 1.20E+02 | 99.631% | 99.631% | 1.17E+01 | 9.95E-01 | 1.19E+02 | 99.339% | |
18 | 1404.66 | 0.0070099 | 100% | 1.00 | 3.88E+00 | 1.00 | 120.12 | 100% | 4.07E+00 | 1.00 | 120.12 | 100% | 4.37E+00 | 1.00 | 120.13 | 100% | 4.72E+00 | 1.00 | 120.14 | 100% | 5.41E+00 | 1.00 | 120.15 | 100% | 6.01E+00 | 1.00 | 120.16 | 100% | 6.95E+00 | 1.00 | 120.17 | 100% | 6.87E+00 | 1.00 | 120.17 | 100% | 6.24E+00 | 1.00 | 120.16 | 100% | 5.06E+00 | 1.00 | 120.14 | 100% | 4.26E+00 | 1.00 | 120.13 | 100% | 3.83E+00 | 1.00 | 120.12 | 100% | 100.1% | 1.18E+01 | 1.00 | 120.23 | 100% | |||
19 | assume xylene is m-xylene, lowest boiling point | 0.563 | psi | 0.590 | psi | 0.634 | psi | 0.685 | psi | 0.785 | psi | 0.872 | psi | 1.008 | psi | 0.996 | psi | 0.906 | psi | 0.734 | psi | 0.618 | psi | 0.555 | psi | 1.707 | psi | |||||||||||||||||||||||||||||||||
20 | assume cresols are o-cresol, lowest boiling point | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
21 | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
22 | 95 F Max | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
23 | Solution Conditions | R | 501.40 | 503.45 | 506.65 | 510.10 | 516.30 | 521.15 | 528.05 | 527.50 | 522.95 | 513.25 | 505.50 | 500.85 | 554.67 | |||||||||||||||||||||||||||||||||||||||||||||
24 | Solution Temperature | ºC | 5.41 | 6.54 | 8.32 | 10.24 | 13.68 | 16.38 | 20.21 | 19.91 | 17.38 | 11.99 | 7.68 | 5.10 | 35.00 | |||||||||||||||||||||||||||||||||||||||||||||
25 | Atmospheric Pressure | psi | 0.563 | 0.590 | 0.634 | 0.685 | 0.785 | 0.872 | 1.008 | 0.996 | 0.906 | 0.734 | 0.618 | 0.555 | psi | |||||||||||||||||||||||||||||||||||||||||||||
26 | Vapor Molecular Weight | Mv | 120.12 | 120.12 | 120.13 | 120.14 | 120.15 | 120.16 | 120.17 | 120.17 | 120.16 | 120.14 | 120.13 | 120.12 | 1.00 | |||||||||||||||||||||||||||||||||||||||||||||
27 | Pure Vapor Pressure Calculation | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
28 | Component | Antoine's Coefficients (1) | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
29 | A | B | C | kPa | kPa | kPa | kPa | kPa | kPa | kPa | kPa | kPa | kPa | kPa | kPa | kPa | ||||||||||||||||||||||||||||||||||||||||||||
30 | 00091-57-6 | 2-Methyl naphthalene | 4.19 | 1840.27 | -74.76 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.01 | 0.01 | 0.00 | 0.00 | 0.00 | 0.00 | 0.02 | ||||||||||||||||||||||||||||||||||||||||||
31 | 00091-20-3 | Naphthalene | 7.15 | 1831.60 | 211.82 | 0.01 | 0.01 | 0.01 | 0.01 | 0.01 | 0.02 | 0.02 | 0.02 | 0.02 | 0.01 | 0.01 | 0.01 | 0.07 | ||||||||||||||||||||||||||||||||||||||||||
32 | 00108-95-2 | Phenol | 7.12 | 1509.70 | 174.20 | 0.01 | 0.01 | 0.01 | 0.01 | 0.02 | 0.02 | 0.03 | 0.03 | 0.02 | 0.01 | 0.01 | 0.01 | 0.11 | ||||||||||||||||||||||||||||||||||||||||||
33 | 00095-48-7 | Cresols (mixture), including m-cresol, o-cresol, p-cresol | 6.84 | 1391.30 | 160.18 | 0.00 | 0.00 | 0.01 | 0.01 | 0.01 | 0.01 | 0.02 | 0.02 | 0.01 | 0.01 | 0.00 | 0.00 | 0.07 | ||||||||||||||||||||||||||||||||||||||||||
34 | 00071-43-2 | Benzene | 6.91 | 1211.00 | 220.79 | 4.75 | 5.06 | 5.56 | 6.15 | 7.35 | 8.41 | 10.14 | 9.99 | 8.84 | 6.74 | 5.38 | 4.68 | 19.79 | ||||||||||||||||||||||||||||||||||||||||||
35 | 00100-41-4 | Ethyl benzene | 6.95 | 1419.30 | 212.61 | 0.37 | 0.40 | 0.45 | 0.51 | 0.64 | 0.75 | 0.95 | 0.93 | 0.80 | 0.57 | 0.43 | 0.36 | 2.20 | ||||||||||||||||||||||||||||||||||||||||||
36 | 00098-82-8 | Isopropylbenzene (Cumene) | 6.93 | 1455.80 | 207.20 | 0.16 | 0.17 | 0.20 | 0.23 | 0.29 | 0.35 | 0.45 | 0.44 | 0.37 | 0.26 | 0.19 | 0.16 | 1.10 | ||||||||||||||||||||||||||||||||||||||||||
37 | 00108-88-3 | Toluene | 7.02 | 1377.60 | 222.64 | 1.26 | 1.35 | 1.50 | 1.68 | 2.05 | 2.39 | 2.95 | 2.90 | 2.53 | 1.86 | 1.45 | 1.24 | 6.24 | ||||||||||||||||||||||||||||||||||||||||||
38 | 00110-54-3 | Hexane | 6.88 | 1171.50 | 224.37 | 8.03 | 8.50 | 9.30 | 10.22 | 12.07 | 13.70 | 16.33 | 16.11 | 14.35 | 11.13 | 9.01 | 7.90 | 30.63 | ||||||||||||||||||||||||||||||||||||||||||
39 | 00108-38-3 | Xylene (mixture), including m-xylene, o-xylene, p-xylene | 7.01 | 1462.30 | 215.11 | 0.32 | 0.34 | 0.39 | 0.44 | 0.55 | 0.66 | 0.83 | 0.82 | 0.70 | 0.50 | 0.37 | 0.31 | 1.94 | ||||||||||||||||||||||||||||||||||||||||||
40 | 07783-06-4 | Hydrogen sulfide | 4.53 | 958.59 | -0.54 | 1,204.82 | 1,244.48 | 1,308.33 | 1,379.87 | 1,515.70 | 1,628.66 | 1,799.93 | 1,785.81 | 1,672.13 | 1,447.70 | 1,285.11 | 1,194.34 | 2,586.06 | ||||||||||||||||||||||||||||||||||||||||||
41 | Oil (Fuel oil No. 2 basis) | 12.10 | 8907.00 | 0.02393 | 0.02573 | 0.02877 | 0.03240 | 0.03996 | 0.04692 | 0.05866 | 0.05764 | 0.04976 | 0.03607 | 0.02764 | 0.02347 | 0.13180 | ||||||||||||||||||||||||||||||||||||||||||||
42 | Oil (JP-4 basis) | 11.37 | 5,784.30 | 5.82675 | 6.10699 | 6.56663 | 7.09377 | 8.12859 | 9.02186 | 10.42995 | 10.31150 | 9.37319 | 7.60504 | 6.39827 | 5.75340 | 17.64399 | ||||||||||||||||||||||||||||||||||||||||||||
43 | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
44 |
(1) Antoine's Coefficients for EG, PH and ET are from AP-42,
Section 7.1, Organic Liquid Storage Tanks, June 2020, Table 7.1-3;
Antoine's equation is log Piº = A - B/(T+C), where T is in ºC and Piº is in mmHg. Antoine's equation is ln Piº = A + B/(T+C), where T is in K and Piº is in kPa. |
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45 | 10^(A-(B/(C+T+273.15)))*100 | K, bar | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
46 | (10^(A-(B/(T+C))))*0.13332239 | C, mmHg | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
47 | EXP(A+(B/(T+273.15+C))) | K, kPa | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
48 | (exp(A-(B/(T))))*101.325/14.696 | R, psia | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
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A | B | C | D | E | F | G | H | I | J | K | L | M | N | O | P | Q | R | S | T | U | V | W | X | Y | Z | AA | AB | AC | AD | AE | AF | AG | AH | AI | AJ | AK | AL | AM | AN | AO | AP | AQ | AR | AS | AT | AU | AV | AW | AX | AY | AZ | BA | BB | BC | BD | BE | BF | BG | BH | |
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1 | January | February | March | April | May | June | July | August | September | October | November | December | Annual | Max of 95 F | ||||||||||||||||||||||||||||||||||||||||||||||
2 | Solution Composition | 501.40 | 503.45 | 506.65 | 510.10 | 516.30 | 521.15 | 528.05 | 527.50 | 522.95 | 513.25 | 505.50 | 500.85 | 554.67 | ||||||||||||||||||||||||||||||||||||||||||||||
3 | CAS # | Component | Weight % in Liquid Phase |
MW (lb/lb-mole) |
No. Moles |
Mole % in Liquid Phase |
Liquid Mole Fraction (Xi) (1) | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase | Max of any month | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase |
4 | 00067-56-1 | Methanol | 8% | 32.04 | 0.0024969 | 4.66% | 0.05 | 2.63E-01 | 0.24 | 7.665 | 35.860% | 2.82E-01 | 0.24 | 7.599 | 35.599% | 3.13E-01 | 0.23 | 7.498 | 35.201% | 3.50E-01 | 0.23 | 7.393 | 34.783% | 4.27E-01 | 0.23 | 7.212 | 34.059% | 4.97E-01 | 0.22 | 7.078 | 33.516% | 6.13E-01 | 2.15E-01 | 6.90E+00 | 32.778% | 6.03E-01 | 2.16E-01 | 6.91E+00 | 32.835% | 5.25E-01 | 2.19E-01 | 7.03E+00 | 33.320% | 3.88E-01 | 2.28E-01 | 7.30E+00 | 34.411% | 3.01E-01 | 2.35E-01 | 7.53E+00 | 35.343% | 2.58E-01 | 2.40E-01 | 7.68E+00 | 35.930% | 35.930% | 1.30E+00 | 1.96E-01 | 6.28E+00 | 30.258% |
5 | Water | 92% | 18 | 0.0510544 | 95.34% | 0.95 | 8.36E-01 | 0.76 | 13.709 | 64.140% | 9.06E-01 | 0.76 | 13.746 | 64.401% | 1.02E+00 | 0.77 | 13.803 | 64.799% | 1.17E+00 | 0.77 | 13.862 | 65.217% | 1.47E+00 | 0.77 | 13.964 | 65.941% | 1.75E+00 | 0.78 | 14.039 | 66.484% | 2.23E+00 | 7.85E-01 | 1.41E+01 | 67.222% | 2.19E+00 | 7.84E-01 | 1.41E+01 | 67.165% | 1.87E+00 | 7.81E-01 | 1.41E+01 | 66.680% | 1.31E+00 | 7.72E-01 | 1.39E+01 | 65.589% | 9.80E-01 | 7.65E-01 | 1.38E+01 | 64.657% | 8.18E-01 | 7.60E-01 | 1.37E+01 | 64.070% | 67.222% | 5.34E+00 | 8.04E-01 | 1.45E+01 | 69.742% | |
6 | 0% | 0 | 0 | 0.00% | 0.00 | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | ||
7 | 0% | 0 | 0 | 0.00% | 0.00 | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | ||
8 | 0% | 0 | 0 | 0.00% | 0.00 | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | ||
9 | 0% | 0 | 0 | 0.00% | 0.00 | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | ||
10 | 0% | 0 | 0 | 0.00% | 0.00 | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | ||
11 | 0% | 0 | 0 | 0.00% | 0.00 | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | ||
12 | 0% | 0 | 0 | 0.00% | 0.00 | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | ||
13 | 0% | 0 | 0 | 0.00% | 0.00 | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | ||
14 | 0% | 0 | 0 | 0.00% | 0.00 | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | ||
15 | 0% | 0 | 0 | 0.00% | 0.00 | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | ||
16 | 0% | 0 | 0 | 0.00% | 0.00 | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | ||
17 | 0.0535513 | 100% | 1.00 | 1.10E+00 | 1.00 | 21.37 | 100% | 1.19E+00 | 1.00 | 21.35 | 100% | 1.34E+00 | 1.00 | 21.30 | 100% | 1.52E+00 | 1.00 | 21.26 | 100% | 1.90E+00 | 1.00 | 21.18 | 100% | 2.25E+00 | 1.00 | 21.12 | 100% | 2.85E+00 | 1.00 | 21.04 | 100% | 2.80E+00 | 1.00 | 21.04 | 100% | 2.39E+00 | 1.00 | 21.10 | 100% | 1.70E+00 | 1.00 | 21.21 | 100% | 1.28E+00 | 1.00 | 21.32 | 100% | 1.08E+00 | 1.00 | 21.38 | 100% | 103.2% | 6.64E+00 | 1.00 | 20.77 | 100% | ||||
18 | 0.1594 | psi | 0.1722 | psi | 0.1940 | psi | 0.2202 | psi | 0.2752 | psi | 0.3262 | psi | 0.4130 | psi | 0.4054 | psi | 0.3472 | psi | 0.2468 | psi | 0.1859 | psi | 0.1561 | psi | 0.9637 | psi | ||||||||||||||||||||||||||||||||||
19 | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
20 | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
21 | 95 F Max | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
22 | Solution Conditions | 536.67 | R | R | 501.40 | 503.45 | 506.65 | 510.10 | 516.30 | 521.15 | 528.05 | 527.50 | 522.95 | 513.25 | 505.50 | 500.85 | 554.67 | |||||||||||||||||||||||||||||||||||||||||||
23 | Solution Temperature | 25.00 | ºC | C | 5.41 | 6.54 | 8.32 | 10.24 | 13.68 | 16.38 | 20.21 | 19.91 | 17.38 | 11.99 | 7.68 | 5.10 | 35.00 | |||||||||||||||||||||||||||||||||||||||||||
24 | Atmospheric Pressure | 101.325 | kPa | psi | 0.159 | 0.172 | 0.194 | 0.220 | 0.275 | 0.326 | 0.413 | 0.405 | 0.347 | 0.247 | 0.186 | 0.156 | 0.964 | |||||||||||||||||||||||||||||||||||||||||||
25 | Mv | 21.37 | 21.35 | 21.30 | 21.26 | 21.18 | 21.12 | 21.04 | 21.04 | 21.10 | 21.21 | 21.32 | 21.38 | 1.00 | ||||||||||||||||||||||||||||||||||||||||||||||
26 | Pure Vapor Pressure Calculation | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
27 | CAS # | Component | Antoine's Coefficients (1) | Pure Vapor Pressure (Piº) | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||
28 | A | B | C | kPa | mmHg | kPa | kPa | kPa | kPa | kPa | kPa | kPa | kPa | kPa | kPa | kPa | kPa | kPa | ||||||||||||||||||||||||||||||||||||||||||
29 | 00067-56-1 | Methanol | 8.08 | 1581.30 | 239.65 | 16.94 | 127.04 | 5.64 | 6.04 | 6.71 | 7.51 | 9.16 | 10.66 | 13.14 | 12.93 | 11.26 | 8.32 | 6.46 | 5.53 | 27.95 | ||||||||||||||||||||||||||||||||||||||||
30 | Water | 16.29 | -3816.44 | -46.13 | 3.14 | 23.57 | 0.88 | 0.95 | 1.07 | 1.23 | 1.54 | 1.84 | 2.34 | 2.30 | 1.96 | 1.38 | 1.03 | 0.86 | 5.60 | |||||||||||||||||||||||||||||||||||||||||
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43 |
(1) Antoine's Coefficients for EG, PH and ET are from AP-42,
Section 7.1, Organic Liquid Storage Tanks, June 2020, Table 7.1-3;
Antoine's equation is log Piº = A - B/(T+C), where T is in ºC and Piº is in mmHg. Antoine's equation is ln Piº = A + B/(T+C), where T is in K and Piº is in kPa. |
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44 | 10^(A-(B/(C+T+273.15)))*100 | K, bar | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
45 | (10^(A-(B/(T+C))))*0.13332239 | C, mmHg | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
46 | EXP(A+(B/(T+273.15+C))) | K, kPa | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
47 | (exp(A-(B/(T))))*101.325/14.696 | R, psia | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
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A | B | C | D | E | F | G | H | I | J | K | L | M | N | O | P | Q | R | S | T | U | V | W | X | Y | Z | AA | AB | AC | AD | AE | AF | AG | AH | AI | AJ | AK | AL | AM | AN | AO | AP | AQ | AR | AS | AT | AU | AV | AW | AX | AY | AZ | BA | BB | BC | BD | BE | BF | BG | BH | |
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1 | January | February | March | April | May | June | July | August | September | October | November | December | Annual | Max of 95 F | ||||||||||||||||||||||||||||||||||||||||||||||
2 | Solution Composition | 501.40 | 503.45 | 506.65 | 510.10 | 516.30 | 521.15 | 528.05 | 527.50 | 522.95 | 513.25 | 505.50 | 500.85 | 554.67 | ||||||||||||||||||||||||||||||||||||||||||||||
3 | CAS # | Component | Weight % in Liquid Phase |
MW (lb/lb-mole) |
No. Moles |
Mole % in Liquid Phase |
Liquid Mole Fraction (Xi) (1) | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase | Max of any month | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase |
4 | 00107-21-1 | Ethylene glycol | 95% | 62.07 | 0.0153058 | 97.01% | 0.97 | 1.16E-03 | 1.00 | 62.050 | 99.951% | 1.32E-03 | 1.00 | 62.049 | 99.948% | 1.62E-03 | 1.00 | 62.047 | 99.943% | 2.02E-03 | 1.00 | 62.045 | 99.937% | 2.95E-03 | 1.00 | 62.041 | 99.927% | 3.93E-03 | 1.00 | 62.038 | 99.918% | 5.84E-03 | 9.99E-01 | 6.20E+01 | 99.904% | 5.66E-03 | 9.99E-01 | 6.20E+01 | 99.905% | 4.36E-03 | 9.99E-01 | 6.20E+01 | 99.914% | 2.45E-03 | 1.00E+00 | 6.20E+01 | 99.932% | 1.51E-03 | 1.00E+00 | 6.20E+01 | 99.945% | 1.12E-03 | 1.00E+00 | 6.21E+01 | 99.951% | 99.951% | 2.37E-02 | 9.99E-01 | 6.20E+01 | 99.838% |
5 | 00111-46-6 | Diethylene glycol | 5% | 106.12 | 0.0004712 | 2.99% | 0.03 | 3.35E-07 | 0.00 | 0.031 | 0.049% | 4.05E-07 | 0.00 | 0.032 | 0.052% | 5.43E-07 | 0.00 | 0.035 | 0.057% | 7.40E-07 | 0.00 | 0.039 | 0.063% | 1.27E-06 | 0.00 | 0.046 | 0.073% | 1.90E-06 | 0.00 | 0.051 | 0.082% | 3.30E-06 | 5.65E-04 | 5.99E-02 | 0.096% | 3.16E-06 | 5.58E-04 | 5.92E-02 | 0.095% | 2.20E-06 | 5.03E-04 | 5.34E-02 | 0.086% | 9.75E-07 | 3.98E-04 | 4.22E-02 | 0.068% | 4.89E-07 | 3.24E-04 | 3.44E-02 | 0.055% | 3.18E-07 | 2.84E-04 | 3.02E-02 | 0.049% | 0.096% | 2.26E-05 | 9.49E-04 | 1.01E-01 | 0.162% |
6 | Water | 0% | 18.02 | 0 | 0.00% | 0.00 | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | |
7 | 0% | 0 | 0 | 0.00% | 0.00 | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | ||
8 | 0% | 0 | 0 | 0.00% | 0.00 | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | ||
9 | 0% | 0 | 0 | 0.00% | 0.00 | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | ||
10 | 0% | 0 | 0 | 0.00% | 0.00 | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | ||
11 | 0% | 0 | 0 | 0.00% | 0.00 | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | ||
12 | 0% | 0 | 0 | 0.00% | 0.00 | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | ||
13 | 0% | 0 | 0 | 0.00% | 0.00 | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | ||
14 | 0% | 0 | 0 | 0.00% | 0.00 | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | ||
15 | 0% | 0 | 0 | 0.00% | 0.00 | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | ||
16 | 0% | 0 | 0 | 0.00% | 0.00 | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | ||
17 | 0.0157770 | 100% | 1.00 | 1.16E-03 | 1.00 | 62.08 | 100% | 1.32E-03 | 1.00 | 62.08 | 100% | 1.62E-03 | 1.00 | 62.08 | 100% | 2.02E-03 | 1.00 | 62.08 | 100% | 2.95E-03 | 1.00 | 62.09 | 100% | 3.93E-03 | 1.00 | 62.09 | 100% | 5.85E-03 | 1.00 | 62.09 | 100% | 5.67E-03 | 1.00 | 62.09 | 100% | 4.37E-03 | 1.00 | 62.09 | 100% | 2.45E-03 | 1.00 | 62.09 | 100% | 1.51E-03 | 1.00 | 62.08 | 100% | 1.12E-03 | 1.00 | 62.08 | 100% | 100.0% | 2.38E-02 | 1.00 | 62.11 | 100% | ||||
18 | 0.0002 | psi | 0.0002 | psi | 0.0002 | psi | 0.0003 | psi | 0.0004 | psi | 0.0006 | psi | 0.0008 | psi | 0.0008 | psi | 0.0006 | psi | 0.0004 | psi | 0.0002 | psi | 0.0002 | psi | 0.0034 | psi | ||||||||||||||||||||||||||||||||||
19 | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
20 | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
21 | 95 F Max | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
22 | Solution Conditions | 536.67 | R | R | 501.40 | 503.45 | 506.65 | 510.10 | 516.30 | 521.15 | 528.05 | 527.50 | 522.95 | 513.25 | 505.50 | 500.85 | 554.67 | |||||||||||||||||||||||||||||||||||||||||||
23 | Solution Temperature | 25.00 | ºC | C | 5.41 | 6.54 | 8.32 | 10.24 | 13.68 | 16.38 | 20.21 | 19.91 | 17.38 | 11.99 | 7.68 | 5.10 | 35.00 | |||||||||||||||||||||||||||||||||||||||||||
24 | Atmospheric Pressure | 101.325 | kPa | psi | 0.0002 | 0.0002 | 0.0002 | 0.0003 | 0.0004 | 0.0006 | 0.0008 | 0.0008 | 0.0006 | 0.0004 | 0.0002 | 0.0002 | 0.0034 | |||||||||||||||||||||||||||||||||||||||||||
25 | Mv | 62.08 | 62.08 | 62.08 | 62.08 | 62.09 | 62.09 | 62.09 | 62.09 | 62.09 | 62.09 | 62.08 | 62.08 | 1.00 | ||||||||||||||||||||||||||||||||||||||||||||||
26 | Pure Vapor Pressure Calculation | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
27 | CAS # | Component | Antoine's Coefficients (1) | Pure Vapor Pressure (Piº) | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||
28 | A | B | C | kPa | mmHg | kPa | kPa | kPa | kPa | kPa | kPa | kPa | kPa | kPa | kPa | kPa | kPa | kPa | ||||||||||||||||||||||||||||||||||||||||||
29 | 00107-21-1 | Ethylene glycol | 4.97 | 1914.95 | -85.00 | 0.01 | 0.07 | 0.001 | 0.001 | 0.002 | 0.002 | 0.003 | 0.004 | 0.006 | 0.006 | 0.004 | 0.003 | 0.002 | 0.001 | 0.024 | ||||||||||||||||||||||||||||||||||||||||
30 | 00111-46-6 | Diethylene glycol | 17.03 | 4122.52 | -122.50 | 2.13E-04 | 1.60E-03 | 1.12E-05 | 1.36E-05 | 1.82E-05 | 2.48E-05 | 4.24E-05 | 6.35E-05 | 1.11E-04 | 1.06E-04 | 7.36E-05 | 3.26E-05 | 1.64E-05 | 1.06E-05 | 7.55E-04 | ||||||||||||||||||||||||||||||||||||||||
31 | Water | 16.29 | -3816.44 | -46.13 | 3.14 | 23.57 | 0.88 | 0.95 | 1.07 | 1.23 | 1.54 | 1.84 | 2.34 | 2.30 | 1.96 | 1.38 | 1.03 | 0.86 | 5.60 | |||||||||||||||||||||||||||||||||||||||||
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43 |
(1) Antoine's Coefficients for EG, PH and ET are from AP-42,
Section 7.1, Organic Liquid Storage Tanks, June 2020, Table 7.1-3;
Antoine's equation is log Piº = A - B/(T+C), where T is in ºC and Piº is in mmHg. Antoine's equation is ln Piº = A + B/(T+C), where T is in K and Piº is in kPa. |
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44 | 10^(A-(B/(C+T+273.15)))*100 | K, bar | Ethyelene glycol antoine constants from https://webbook.nist.gov/cgi/cbook.cgi?ID=C107211&Mask=4&Type=ANTOINE&Plot=on | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||
45 | (10^(A-(B/(T+C))))*0.13332239 | C, mmHg | Diethylene glycol antoine constants from https://www.matweb.com/search/datasheet.aspx?matguid=4f3bef5f67984f4abc5529c0e93278bf&n=1&ckck=1 | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||
46 | EXP(A+(B/(T+273.15+C))) | K, kPa | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
47 | (exp(A-(B/(T))))*101.325/14.696 | R, psia | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
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A | B | C | D | E | F | G | H | I | J | K | L | M | N | O | P | Q | R | S | T | U | V | W | X | Y | Z | AA | AB | AC | AD | AE | AF | AG | AH | AI | AJ | AK | AL | AM | AN | AO | AP | AQ | AR | AS | AT | AU | AV | AW | AX | AY | AZ | BA | BB | BC | BD | BE | BF | BG | BH | |
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1 | January | February | March | April | May | June | July | August | September | October | November | December | Annual | Max of 95 F | ||||||||||||||||||||||||||||||||||||||||||||||
2 | Solution Composition | 501.40 | 503.45 | 506.65 | 510.10 | 516.30 | 521.15 | 528.05 | 527.50 | 522.95 | 513.25 | 505.50 | 500.85 | 554.67 | ||||||||||||||||||||||||||||||||||||||||||||||
3 | CAS # | Component | Weight % in Liquid Phase |
MW (lb/lb-mole) |
No. Moles |
Mole % in Liquid Phase |
Liquid Mole Fraction (Xi) (1) | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase | Max of any month | Vapor Partial Pressure (Pi) (kPa) (2) | Vapor Mole Fraction (Yi) (3) | Pounds in Vapor Phase (lb) | Weight % in Vapor Phase |
4 | 00107-21-1 | Ethylene glycol | 55% | 62.07 | 0.0088613 | 94.95% | 0.95 | 1.13E-03 | 1.00 | 62.037 | 99.915% | 1.29E-03 | 1.00 | 62.035 | 99.910% | 1.59E-03 | 1.00 | 62.032 | 99.901% | 1.97E-03 | 1.00 | 62.028 | 99.892% | 2.88E-03 | 1.00 | 62.022 | 99.873% | 3.85E-03 | 1.00 | 62.016 | 99.858% | 5.72E-03 | 9.99E-01 | 6.20E+01 | 99.833% | 5.54E-03 | 9.99E-01 | 6.20E+01 | 99.835% | 4.27E-03 | 9.99E-01 | 6.20E+01 | 99.852% | 2.40E-03 | 9.99E-01 | 6.20E+01 | 99.883% | 1.48E-03 | 9.99E-01 | 6.20E+01 | 99.904% | 1.09E-03 | 1.00E+00 | 6.20E+01 | 99.916% | 99.916% | 2.32E-02 | 9.98E-01 | 6.20E+01 | 99.720% |
5 | Diethylene glycol | 5% | 106.12 | 0.0004712 | 5.05% | 0.05 | 5.66E-07 | 0.00 | 0.053 | 0.085% | 6.85E-07 | 0.00 | 0.056 | 0.090% | 9.18E-07 | 0.00 | 0.061 | 0.099% | 1.25E-06 | 0.00 | 0.067 | 0.108% | 2.14E-06 | 0.00 | 0.079 | 0.127% | 3.21E-06 | 0.00 | 0.088 | 0.142% | 5.58E-06 | 9.75E-04 | 1.03E-01 | 0.167% | 5.34E-06 | 9.63E-04 | 1.02E-01 | 0.165% | 3.71E-06 | 8.69E-04 | 9.22E-02 | 0.148% | 1.65E-06 | 6.87E-04 | 7.29E-02 | 0.117% | 8.27E-07 | 5.60E-04 | 5.94E-02 | 0.096% | 5.37E-07 | 4.91E-04 | 5.21E-02 | 0.084% | 0.167% | 3.81E-05 | 1.64E-03 | 1.74E-01 | 0.280% | |
6 | Water | 40% | 18.02 | 0 | 0.00% | 0.00 | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | |
7 | 0% | 0 | 0 | 0.00% | 0.00 | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | ||
8 | 0% | 0 | 0 | 0.00% | 0.00 | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | ||
9 | 0% | 0 | 0 | 0.00% | 0.00 | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | ||
10 | 0% | 0 | 0 | 0.00% | 0.00 | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | ||
11 | 0% | 0 | 0 | 0.00% | 0.00 | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | ||
12 | 0% | 0 | 0 | 0.00% | 0.00 | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | ||
13 | 0% | 0 | 0 | 0.00% | 0.00 | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | ||
14 | 0% | 0 | 0 | 0.00% | 0.00 | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | ||
15 | 0% | 0 | 0 | 0.00% | 0.00 | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | ||
16 | 0% | 0 | 0 | 0.00% | 0.00 | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00 | 0.000 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | 0.000% | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.000% | ||
17 | 0.0093324 | 100% | 1.00 | 1.13E-03 | 1.00 | 62.09 | 100% | 1.30E-03 | 1.00 | 62.09 | 100% | 1.59E-03 | 1.00 | 62.09 | 100% | 1.98E-03 | 1.00 | 62.10 | 100% | 2.89E-03 | 1.00 | 62.10 | 100% | 3.85E-03 | 1.00 | 62.10 | 100% | 5.72E-03 | 1.00 | 62.11 | 100% | 5.55E-03 | 1.00 | 62.11 | 100% | 4.28E-03 | 1.00 | 62.11 | 100% | 2.40E-03 | 1.00 | 62.10 | 100% | 1.48E-03 | 1.00 | 62.09 | 100% | 1.09E-03 | 1.00 | 62.09 | 100% | 100.1% | 2.33E-02 | 1.00 | 62.14 | 100% | ||||
18 | 0.0002 | psi | 0.0002 | psi | 0.0002 | psi | 0.0003 | psi | 0.0004 | psi | 0.0006 | psi | 0.0008 | psi | 0.0008 | psi | 0.0006 | psi | 0.0003 | psi | 0.0002 | psi | 0.0002 | psi | 0.0034 | psi | ||||||||||||||||||||||||||||||||||
19 | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
20 | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
21 | 95 F Max | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
22 | Solution Conditions | 536.67 | R | R | 501.40 | 503.45 | 506.65 | 510.10 | 516.30 | 521.15 | 528.05 | 527.50 | 522.95 | 513.25 | 505.50 | 500.85 | 554.67 | |||||||||||||||||||||||||||||||||||||||||||
23 | Solution Temperature | 25.00 | ºC | C | 5.41 | 6.54 | 8.32 | 10.24 | 13.68 | 16.38 | 20.21 | 19.91 | 17.38 | 11.99 | 7.68 | 5.10 | 35.00 | |||||||||||||||||||||||||||||||||||||||||||
24 | Atmospheric Pressure | 101.325 | kPa | psi | 0.0002 | 0.0002 | 0.0002 | 0.0003 | 0.0004 | 0.0006 | 0.0008 | 0.0008 | 0.0006 | 0.0003 | 0.0002 | 0.0002 | 0.0034 | |||||||||||||||||||||||||||||||||||||||||||
25 | Mv | 62.09 | 62.09 | 62.09 | 62.10 | 62.10 | 62.10 | 62.11 | 62.11 | 62.11 | 62.10 | 62.09 | 62.09 | 1.00 | ||||||||||||||||||||||||||||||||||||||||||||||
26 | Pure Vapor Pressure Calculation | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
27 | CAS # | Component | Antoine's Coefficients (1) | Pure Vapor Pressure (Piº) | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||
28 | A | B | C | kPa | mmHg | kPa | kPa | kPa | kPa | kPa | kPa | kPa | kPa | kPa | kPa | kPa | kPa | kPa | ||||||||||||||||||||||||||||||||||||||||||
29 | 00107-21-1 | Ethylene glycol | 4.97 | 1914.95 | -85.00 | 0.01 | 0.07 | 0.001 | 0.001 | 0.002 | 0.002 | 0.003 | 0.004 | 0.006 | 0.006 | 0.004 | 0.003 | 0.002 | 0.001 | 0.024 | ||||||||||||||||||||||||||||||||||||||||
30 | Diethylene glycol | 17.03 | 4122.52 | -122.50 | 2.13E-04 | 1.60E-03 | 1.12E-05 | 1.36E-05 | 1.82E-05 | 2.48E-05 | 4.24E-05 | 6.35E-05 | 1.11E-04 | 1.06E-04 | 7.36E-05 | 3.26E-05 | 1.64E-05 | 1.06E-05 | 7.55E-04 | |||||||||||||||||||||||||||||||||||||||||
31 | Water | 16.29 | -3816.44 | -46.13 | 3.14 | 23.57 | 0.88 | 0.95 | 1.07 | 1.23 | 1.54 | 1.84 | 2.34 | 2.30 | 1.96 | 1.38 | 1.03 | 0.86 | 5.60 | |||||||||||||||||||||||||||||||||||||||||
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43 |
(1) Antoine's Coefficients for EG, PH and ET are from AP-42,
Section 7.1, Organic Liquid Storage Tanks, June 2020, Table 7.1-3;
Antoine's equation is log Piº = A - B/(T+C), where T is in ºC and Piº is in mmHg. Antoine's equation is ln Piº = A + B/(T+C), where T is in K and Piº is in kPa. |
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44 | 10^(A-(B/(C+T+273.15)))*100 | K, bar | Ethyelene glycol antoine constants from https://webbook.nist.gov/cgi/cbook.cgi?ID=C107211&Mask=4&Type=ANTOINE&Plot=on | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||
45 | (10^(A-(B/(T+C))))*0.13332239 | C, mmHg | Diethylene glycol antoine constants from https://www.matweb.com/search/datasheet.aspx?matguid=4f3bef5f67984f4abc5529c0e93278bf&n=1&ckck=1 | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||
46 | EXP(A+(B/(T+273.15+C))) | K, kPa | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
47 | (exp(A-(B/(T))))*101.325/14.696 | R, psia | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
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A | B | C | D | E | F | G | H | I | J | K | L | M | N | O | P | Q | R | S | T | U | V | W | X | Y | Z | AA | AB | AC | AD | |
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1 | Attachment B - Emission Calculations | |||||||||||||||||||||||||||||
2 | Table B-4: VOC and TAC Emission from Tanks | |||||||||||||||||||||||||||||
4 | Annual TAC Emissions (lb/yr) | Daily TAC Emissions (lb/day) | ||||||||||||||||||||||||||||
5 | 91-57-6 | 91-20-3 | 108-95-2 | 1319-77-3 | 71-43-2 | 100-41-4 | 98-82-8 | 108-88-3 | 110-54-3 | 1330-20-7 | 7783-06-4 | 67-56-1 | 91-57-6 | 91-20-3 | 108-95-2 | 1319-77-3 | 71-43-2 | 100-41-4 | 98-82-8 | 108-88-3 | 110-54-3 | 1330-20-7 | 7783-06-4 | 67-56-1 | ||||||
6 | TEU ID | Tank ID | Pva | CAO VOC* Emission Rate (lb/yr) | CAO VOC Emission Rate (lb/day) | To Carbon | 2-Methyl naphthalene | Naphthalene | Phenol | Cresols (mixture), including m-cresol, o-cresol, p-cresol | Benzene | Ethyl benzene | Isopropylbenzene (Cumene) | Toluene | Hexane | Xylene (mixture), including m-xylene, o-xylene, p-xylene | Hydrogen sulfide | Methanol | 2-Methyl naphthalene | Naphthalene | Phenol | Cresols (mixture), including m-cresol, o-cresol, p-cresol | Benzene | Ethyl benzene | Isopropylbenzene (Cumene) | Toluene | Hexane | Xylene (mixture), including m-xylene, o-xylene, p-xylene | Hydrogen sulfide | Methanol |
7 | TANKS | JAIL1 | 0.6 | 62.4 | 13.51 | 0 | 0 | 0 | 1.13E-05 | 2.50E-06 | 4.17E-03 | 1.50E-03 | 0 | 1.60E-02 | 9.93E-03 | 7.23E-03 | 0 | 0 | 0 | 0 | 5.10E-06 | 1.22E-06 | 1.04E-03 | 4.44E-04 | 0 | 4.31E-03 | 2.38E-03 | 2.15E-03 | 0 | 0 |
8 | JAIL2 | 0.6 | 62.4 | 13.51 | 0 | 0 | 0 | 1.13E-05 | 2.50E-06 | 4.17E-03 | 1.50E-03 | 0 | 1.60E-02 | 9.93E-03 | 7.23E-03 | 0 | 0 | 0 | 0 | 5.10E-06 | 1.22E-06 | 1.04E-03 | 4.44E-04 | 0 | 4.31E-03 | 2.38E-03 | 2.15E-03 | 0 | 0 | |
9 | JAIL3 | 0.6 | 76.0 | 16.35 | 0 | 0 | 0 | 1.37E-05 | 3.04E-06 | 5.08E-03 | 1.83E-03 | 0 | 1.94E-02 | 1.21E-02 | 8.79E-03 | 0 | 0 | 0 | 0 | 6.17E-06 | 1.48E-06 | 1.26E-03 | 5.37E-04 | 0 | 5.22E-03 | 2.88E-03 | 2.60E-03 | 0 | 0 | |
10 | JAIL4 | 0.6 | 76.0 | 16.35 | 0 | 0 | 0 | 1.37E-05 | 3.04E-06 | 5.08E-03 | 1.83E-03 | 0 | 1.94E-02 | 1.21E-02 | 8.79E-03 | 0 | 0 | 0 | 0 | 6.17E-06 | 1.48E-06 | 1.26E-03 | 5.37E-04 | 0 | 5.22E-03 | 2.88E-03 | 2.60E-03 | 0 | 0 | |
11 | JAIL7 | 0.6 | 62.4 | 13.51 | 0 | 0 | 0 | 1.13E-05 | 2.50E-06 | 4.17E-03 | 1.50E-03 | 0 | 1.60E-02 | 9.93E-03 | 7.23E-03 | 0 | 0 | 0 | 0 | 5.10E-06 | 1.22E-06 | 1.04E-03 | 4.44E-04 | 0 | 4.31E-03 | 2.38E-03 | 2.15E-03 | 0 | 0 | |
12 | JAIL8 | 0.6 | 62.4 | 13.51 | 0 | 0 | 0 | 1.13E-05 | 2.50E-06 | 4.17E-03 | 1.50E-03 | 0 | 1.60E-02 | 9.93E-03 | 7.23E-03 | 0 | 0 | 0 | 0 | 5.10E-06 | 1.22E-06 | 1.04E-03 | 4.44E-04 | 0 | 4.31E-03 | 2.38E-03 | 2.15E-03 | 0 | 0 | |
13 | JAIL9 | 0.6 | 62.4 | 13.51 | 0 | 0 | 0 | 1.13E-05 | 2.50E-06 | 4.17E-03 | 1.50E-03 | 0 | 1.60E-02 | 9.93E-03 | 7.23E-03 | 0 | 0 | 0 | 0 | 5.10E-06 | 1.22E-06 | 1.04E-03 | 4.44E-04 | 0 | 4.31E-03 | 2.38E-03 | 2.15E-03 | 0 | 0 | |
14 | Removed, previous re-addition was incorrect | 0 | 0 | 0 | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0 | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0 | 0 | 0 | 0 | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0 | 0.00E+00 | 0.00E+00 | 0.00E+00 | 0 | 0 | ||||
15 | CT1 | 1 | 75.7 | 21.28 | 0 | 0 | 0 | 1.37E-05 | 3.02E-06 | 5.06E-03 | 1.82E-03 | 0 | 1.93E-02 | 1.20E-02 | 8.76E-03 | 0 | 0 | 0 | 0 | 8.03E-06 | 1.93E-06 | 1.64E-03 | 6.99E-04 | 0 | 6.80E-03 | 3.75E-03 | 3.39E-03 | 0 | 0 | |
16 | CT2 | 1 | 75.7 | 21.28 | 0 | 0 | 0 | 1.37E-05 | 3.02E-06 | 5.06E-03 | 1.82E-03 | 0 | 1.93E-02 | 1.20E-02 | 8.76E-03 | 0 | 0 | 0 | 0 | 8.03E-06 | 1.93E-06 | 1.64E-03 | 6.99E-04 | 0 | 6.80E-03 | 3.75E-03 | 3.39E-03 | 0 | 0 | |
17 | CT3 | 1 | 81.4 | 21.58 | 0 | 0 | 0 | 1.47E-05 | 3.25E-06 | 5.44E-03 | 1.96E-03 | 0 | 2.08E-02 | 1.29E-02 | 9.42E-03 | 0 | 0 | 0 | 0 | 8.15E-06 | 1.96E-06 | 1.66E-03 | 7.09E-04 | 0 | 6.89E-03 | 3.80E-03 | 3.44E-03 | 0 | 0 | |
18 | CT4 | 1 | 79.0 | 22.46 | 0 | 0 | 0 | 1.43E-05 | 3.16E-06 | 5.28E-03 | 1.90E-03 | 0 | 2.02E-02 | 1.26E-02 | 9.14E-03 | 0 | 0 | 0 | 0 | 8.48E-06 | 2.03E-06 | 1.73E-03 | 7.38E-04 | 0 | 7.17E-03 | 3.95E-03 | 3.58E-03 | 0 | 0 | |
19 | CT5 | 1 | 79.0 | 22.46 | 0 | 0 | 0 | 1.43E-05 | 3.16E-06 | 5.28E-03 | 1.90E-03 | 0 | 2.02E-02 | 1.26E-02 | 9.14E-03 | 0 | 0 | 0 | 0 | 8.48E-06 | 2.03E-06 | 1.73E-03 | 7.38E-04 | 0 | 7.17E-03 | 3.95E-03 | 3.58E-03 | 0 | 0 | |
20 | CT6 | 1 | 79.0 | 22.46 | 0 | 0 | 0 | 1.43E-05 | 3.16E-06 | 5.28E-03 | 1.90E-03 | 0 | 2.02E-02 | 1.26E-02 | 9.14E-03 | 0 | 0 | 0 | 0 | 8.48E-06 | 2.03E-06 | 1.73E-03 | 7.38E-04 | 0 | 7.17E-03 | 3.95E-03 | 3.58E-03 | 0 | 0 | |
21 | TANK12 | 1 | 7197.8 | 231.33 | 0 | 0 | 0 | 1.30E-03 | 2.88E-04 | 4.81E-01 | 1.73E-01 | 0 | 1.84E+00 | 1.14E+00 | 8.33E-01 | 0 | 0 | 0 | 0 | 8.73E-05 | 2.10E-05 | 1.78E-02 | 7.60E-03 | 0 | 7.39E-02 | 4.07E-02 | 3.68E-02 | 0 | 0 | |
22 | IT100-1 | 0.8 | 136.8 | 21.08 | 0 | 0 | 0 | 2.47E-05 | 5.47E-06 | 9.15E-03 | 3.29E-03 | 0 | 3.50E-02 | 2.18E-02 | 1.58E-02 | 0 | 0 | 0 | 0 | 7.96E-06 | 1.91E-06 | 1.62E-03 | 6.93E-04 | 0 | 6.73E-03 | 3.71E-03 | 3.36E-03 | 0 | 0 | |
23 | IT220-1 | 0.8 | 113.6 | 20.84 | 0 | 0 | 0 | 2.05E-05 | 4.54E-06 | 7.60E-03 | 2.74E-03 | 0 | 2.90E-02 | 1.81E-02 | 1.32E-02 | 0 | 0 | 0 | 0 | 7.86E-06 | 1.89E-06 | 1.61E-03 | 6.85E-04 | 0 | 6.66E-03 | 3.67E-03 | 3.32E-03 | 0 | 0 | |
24 | IT220-2 | 1 | 107.9 | 22.31 | 0 | 0 | 0 | 1.95E-05 | 4.31E-06 | 7.22E-03 | 2.60E-03 | 0 | 2.76E-02 | 1.72E-02 | 1.25E-02 | 0 | 0 | 0 | 0 | 8.42E-06 | 2.02E-06 | 1.72E-03 | 7.33E-04 | 0 | 7.13E-03 | 3.93E-03 | 3.55E-03 | 0 | 0 | |
25 | TK10401 | 1 | 114.2 | 28.07 | 0 | 0 | 0 | 2.06E-05 | 4.57E-06 | 7.64E-03 | 2.75E-03 | 0 | 2.92E-02 | 1.82E-02 | 1.32E-02 | 0 | 0 | 0 | 0 | 1.06E-05 | 2.54E-06 | 2.16E-03 | 9.23E-04 | 0 | 8.97E-03 | 4.94E-03 | 4.47E-03 | 0 | 0 | |
26 | TK10402 | 1 | 114.2 | 28.07 | 0 | 0 | 0 | 2.06E-05 | 4.57E-06 | 7.64E-03 | 2.75E-03 | 0 | 2.92E-02 | 1.82E-02 | 1.32E-02 | 0 | 0 | 0 | 0 | 1.06E-05 | 2.54E-06 | 2.16E-03 | 9.23E-04 | 0 | 8.97E-03 | 4.94E-03 | 4.47E-03 | 0 | 0 | |
27 | TK10403 | 1 | 114.2 | 28.07 | 0 | 0 | 0 | 2.06E-05 | 4.57E-06 | 7.64E-03 | 2.75E-03 | 0 | 2.92E-02 | 1.82E-02 | 1.32E-02 | 0 | 0 | 0 | 0 | 1.06E-05 | 2.54E-06 | 2.16E-03 | 9.23E-04 | 0 | 8.97E-03 | 4.94E-03 | 4.47E-03 | 0 | 0 | |
28 | TK10404 | 1 | 114.2 | 28.07 | 0 | 0 | 0 | 2.06E-05 | 4.57E-06 | 7.64E-03 | 2.75E-03 | 0 | 2.92E-02 | 1.82E-02 | 1.32E-02 | 0 | 0 | 0 | 0 | 1.06E-05 | 2.54E-06 | 2.16E-03 | 9.23E-04 | 0 | 8.97E-03 | 4.94E-03 | 4.47E-03 | 0 | 0 | |
29 | TK10501 | 1 | 115.4 | 28.07 | 0 | 0 | 0 | 2.09E-05 | 4.61E-06 | 7.72E-03 | 2.78E-03 | 0 | 2.95E-02 | 1.84E-02 | 1.34E-02 | 0 | 0 | 0 | 0 | 1.06E-05 | 2.54E-06 | 2.16E-03 | 9.23E-04 | 0 | 8.97E-03 | 4.94E-03 | 4.47E-03 | 0 | 0 | |
30 | TK10502 | 1 | 115.4 | 28.07 | 0 | 0 | 0 | 2.09E-05 | 4.61E-06 | 7.72E-03 | 2.78E-03 | 0 | 2.95E-02 | 1.84E-02 | 1.34E-02 | 0 | 0 | 0 | 0 | 1.06E-05 | 2.54E-06 | 2.16E-03 | 9.23E-04 | 0 | 8.97E-03 | 4.94E-03 | 4.47E-03 | 0 | 0 | |
31 | SO1 | 1.1 | 47.8 | 6.79 | 0 | 0 | 0 | 8.63E-06 | 1.91E-06 | 3.20E-03 | 1.15E-03 | 0 | 1.22E-02 | 7.60E-03 | 5.53E-03 | 0 | 0 | 0 | 0 | 2.56E-06 | 6.16E-07 | 5.23E-04 | 2.23E-04 | 0 | 2.17E-03 | 1.20E-03 | 1.08E-03 | 0 | 0 | |
32 | SO2 | 1.1 | 47.8 | 6.79 | 0 | 0 | 0 | 8.63E-06 | 1.91E-06 | 3.20E-03 | 1.15E-03 | 0 | 1.22E-02 | 7.60E-03 | 5.53E-03 | 0 | 0 | 0 | 0 | 2.56E-06 | 6.16E-07 | 5.23E-04 | 2.23E-04 | 0 | 2.17E-03 | 1.20E-03 | 1.08E-03 | 0 | 0 | |
33 | MDO1 | 1 | 180.2 | 17.90 | 0 | 0 | 0 | 3.26E-05 | 7.20E-06 | 1.21E-02 | 4.34E-03 | 0 | 4.61E-02 | 2.87E-02 | 2.09E-02 | 0 | 0 | 0 | 0 | 6.75E-06 | 1.62E-06 | 1.38E-03 | 5.88E-04 | 0 | 5.72E-03 | 3.15E-03 | 2.85E-03 | 0 | 0 | |
34 | WWF1 | 0.96 | 6.1 | 0.62 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 6.1 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0.6 | |
35 | Totals for TEU ID: TANKS | 0 | 0 | 0.0017 | 0.00038 | 0.63 | 0.23 | 0 | 2.42 | 1.50 | 1.09 | 0 | 0 | 0 | 0 | 0.00027 | 0.00007 | 0.056 | 0.024 | 0 | 0.23 | 0.13 | 0.12 | 0 | 0 | |||||
36 | TANKS_CONTROLLED | WLE1 | 1.1 | 35.3 | 4.48 | 1 | 1.09E-04 | 2.54E-04 | 0 | 0 | 1.51E-02 | 3.60E-03 | 3.51E-04 | 3.95E-02 | 3.61E-02 | 1.86E-02 | 2.34E+00 | 0 | 2.82E-05 | 5.69E-05 | 0 | 0 | 2.22E-03 | 6.28E-04 | 6.52E-05 | 6.31E-03 | 5.12E-03 | 3.26E-03 | 2.13E-01 | 0 |
37 | PF2 | 1.1 | 9.9 | 1.99 | 1 | 3.08E-05 | 7.15E-05 | 0 | 0 | 4.25E-03 | 1.01E-03 | 9.90E-05 | 1.11E-02 | 1.02E-02 | 5.23E-03 | 6.59E-01 | 0 | 1.25E-05 | 2.53E-05 | 0 | 0 | 9.88E-04 | 2.79E-04 | 2.90E-05 | 2.80E-03 | 2.27E-03 | 1.45E-03 | 9.46E-02 | 0 | |
38 | TK30 | 1 | 8.9 | 1.46 | 1 | 2.75E-05 | 6.38E-05 | 0 | 0 | 3.80E-03 | 9.05E-04 | 8.84E-05 | 9.94E-03 | 9.09E-03 | 4.67E-03 | 5.89E-01 | 0 | 9.15E-06 | 1.85E-05 | 0 | 0 | 7.22E-04 | 2.04E-04 | 2.12E-05 | 2.05E-03 | 1.66E-03 | 1.06E-03 | 6.91E-02 | 0 | |
39 | IT100-2 | 1.1 | 13.2 | 2.99 | 1 | 0 | 0 | 2.38E-06 | 5.26E-07 | 8.81E-04 | 3.17E-04 | 0 | 3.37E-03 | 2.09E-03 | 1.52E-03 | 0 | 0 | 0 | 0 | 1.13E-06 | 2.71E-07 | 2.30E-04 | 9.82E-05 | 0 | 9.54E-04 | 5.26E-04 | 4.76E-04 | 0 | 0 | |
40 | AF1 | 1 | 12.9 | 1.99 | 1 | 0 | 0 | 2.33E-06 | 5.15E-07 | 8.62E-04 | 3.10E-04 | 0 | 3.30E-03 | 2.05E-03 | 1.49E-03 | 0 | 0 | 0 | 0 | 7.52E-07 | 1.80E-07 | 1.53E-04 | 6.55E-05 | 0 | 6.36E-04 | 3.51E-04 | 3.17E-04 | 0 | 0 | |
41 | Totals for TEU ID: TANKS_CONTROLLED, Emission Point TCARBON | 0.00017 | 0.0004 | 0 | 0 | 0.025 | 0.006 | 0.0005 | 0.07 | 0.06 | 0.031 | 3.59 | 0 | 0.00005 | 0.00010 | 0 | 0 | 0.004 | 0.0013 | 0.00012 | 0.013 | 0.010 | 0.007 | 0.38 | 0 | |||||
42 | UOTANKS_CONTROLLED | UO1 | 1.1 | 9.8 | 2.47 | 1 | 3.03E-05 | 7.03E-05 | 0 | 0 | 4.18E-03 | 9.97E-04 | 9.74E-05 | 1.09E-02 | 1.00E-02 | 5.14E-03 | 6.48E-01 | 0 | 1.55E-05 | 3.14E-05 | 0 | 0 | 1.23E-03 | 3.46E-04 | 3.59E-05 | 3.48E-03 | 2.82E-03 | 1.80E-03 | 1.17E-01 | 0 |
43 | UO2 | 1.1 | 9.8 | 2.47 | 1 | 3.03E-05 | 7.03E-05 | 0 | 0 | 4.18E-03 | 9.97E-04 | 9.74E-05 | 1.09E-02 | 1.00E-02 | 5.14E-03 | 6.48E-01 | 0 | 1.55E-05 | 3.14E-05 | 0 | 0 | 1.23E-03 | 3.46E-04 | 3.59E-05 | 3.48E-03 | 2.82E-03 | 1.80E-03 | 1.17E-01 | 0 | |
44 | UO3 | 1.1 | 9.8 | 2.47 | 1 | 3.03E-05 | 7.03E-05 | 0 | 0 | 4.18E-03 | 9.97E-04 | 9.74E-05 | 1.09E-02 | 1.00E-02 | 5.14E-03 | 6.48E-01 | 0 | 1.55E-05 | 3.14E-05 | 0 | 0 | 1.23E-03 | 3.46E-04 | 3.59E-05 | 3.48E-03 | 2.82E-03 | 1.80E-03 | 1.17E-01 | 0 | |
45 | UO4 | 1.1 | 9.8 | 2.47 | 1 | 3.03E-05 | 7.03E-05 | 0 | 0 | 4.18E-03 | 9.97E-04 | 9.74E-05 | 1.09E-02 | 1.00E-02 | 5.14E-03 | 6.48E-01 | 0 | 1.55E-05 | 3.14E-05 | 0 | 0 | 1.23E-03 | 3.46E-04 | 3.59E-05 | 3.48E-03 | 2.82E-03 | 1.80E-03 | 1.17E-01 | 0 | |
46 | UO5 | 1.1 | 9.8 | 2.47 | 1 | 3.03E-05 | 7.03E-05 | 0 | 0 | 4.18E-03 | 9.97E-04 | 9.74E-05 | 1.09E-02 | 1.00E-02 | 5.14E-03 | 6.48E-01 | 0 | 1.55E-05 | 3.14E-05 | 0 | 0 | 1.23E-03 | 3.46E-04 | 3.59E-05 | 3.48E-03 | 2.82E-03 | 1.80E-03 | 1.17E-01 | 0 | |
47 | UO6 | 1.1 | 9.8 | 2.47 | 1 | 3.03E-05 | 7.03E-05 | 0 | 0 | 4.18E-03 | 9.97E-04 | 9.74E-05 | 1.09E-02 | 1.00E-02 | 5.14E-03 | 6.48E-01 | 0 | 1.55E-05 | 3.14E-05 | 0 | 0 | 1.23E-03 | 3.46E-04 | 3.59E-05 | 3.48E-03 | 2.82E-03 | 1.80E-03 | 1.17E-01 | 0 | |
48 | Totals for TEU ID: UOTANKS_CONTROLLED, Emission Point UCARBON | 0.00018 | 0.0004 | 0 | 0 | 0.025 | 0.006 | 0.0006 | 0.07 | 0.06 | 0.031 | 3.89 | 0 | 0.00009 | 0.00019 | 0 | 0 | 0.007 | 0.0021 | 0.00022 | 0.021 | 0.017 | 0.011 | 0.70 | 0 | |||||
50 | * See Tank Emissions Summary | |||||||||||||||||||||||||||||
52 | Tanks Uncontrolled | lb/yr | lb/day | |||||||||||||||||||||||||||
53 | 91-57-6 | 2-Methyl naphthalene | 0 | 0 |
54 | 91-20-3 | Naphthalene | 0 | 0 | ||||||||||||||||||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
55 | 108-95-2 | Phenol | 0.00171 | 0.00027 | ||||||||||||||||||||||||||
56 | 1319-77-3 | Cresols (mixture), including m-cresol, o-cresol, p-cresol | 0.00038 | 0.00007 | ||||||||||||||||||||||||||
57 | 71-43-2 | Benzene | 0.632 | 0.056 | ||||||||||||||||||||||||||
58 | 100-41-4 | Ethyl benzene | 0.228 | 0.024 | ||||||||||||||||||||||||||
59 | 98-82-8 | Isopropylbenzene (Cumene) | 0 | 0 | ||||||||||||||||||||||||||
60 | 108-88-3 | Toluene | 2.42 | 0.23 | ||||||||||||||||||||||||||
61 | 110-54-3 | Hexane | 1.50 | 0.13 | ||||||||||||||||||||||||||
62 | 1330-20-7 | Xylene (mixture), including m-xylene, o-xylene, p-xylene | 1.09 | 0.12 | ||||||||||||||||||||||||||
63 | 7783-06-4 | Hydrogen sulfide | 0 | 1 | ||||||||||||||||||||||||||
65 | Tanks Controlled | lb/yr | lb/day | |||||||||||||||||||||||||||
66 | 91-57-6 | 2-Methyl naphthalene | 0.00017 | 0.00005 | ||||||||||||||||||||||||||
67 | 91-20-3 | Naphthalene | 0.0004 | 0.0001 | ||||||||||||||||||||||||||
68 | 108-95-2 | Phenol | 0.0000047 | 0.0000019 | ||||||||||||||||||||||||||
69 | 1319-77-3 | Cresols (mixture), including m-cresol, o-cresol, p-cresol | 0.0000010 | 0.0000005 | ||||||||||||||||||||||||||
70 | 71-43-2 | Benzene | 0.025 | 0.004 | ||||||||||||||||||||||||||
71 | 100-41-4 | Ethyl benzene | 0.006 | 0.001 | ||||||||||||||||||||||||||
72 | 98-82-8 | Isopropylbenzene (Cumene) | 0.0005 | 0.0001 | ||||||||||||||||||||||||||
73 | 108-88-3 | Toluene | 0.067 | 0.013 | ||||||||||||||||||||||||||
74 | 110-54-3 | Hexane | 0.06 | 0.01 | ||||||||||||||||||||||||||
75 | 1330-20-7 | Xylene (mixture), including m-xylene, o-xylene, p-xylene | 0.031 | 0.007 | ||||||||||||||||||||||||||
76 | 7783-06-4 | Hydrogen sulfide | 0.00 | 0.00 | ||||||||||||||||||||||||||
78 | UO Tanks Controlled | lb/yr | lb/day | |||||||||||||||||||||||||||
79 | 91-57-6 | 2-Methyl naphthalene | 0.00018 | 0.00009 | ||||||||||||||||||||||||||
80 | 91-20-3 | Naphthalene | 0.0004 | 0.0002 | ||||||||||||||||||||||||||
81 | 108-95-2 | Phenol | 0 | 0 | ||||||||||||||||||||||||||
82 | 1319-77-3 | Cresols (mixture), including m-cresol, o-cresol, p-cresol | 0 | 0 | ||||||||||||||||||||||||||
83 | 71-43-2 | Benzene | 0.025 | 0.007 | ||||||||||||||||||||||||||
84 | 100-41-4 | Ethyl benzene | 0.006 | 0.002 | ||||||||||||||||||||||||||
85 | 98-82-8 | Isopropylbenzene (Cumene) | 0.0006 | 0.0002 | ||||||||||||||||||||||||||
86 | 108-88-3 | Toluene | 0.066 | 0.021 | ||||||||||||||||||||||||||
87 | 110-54-3 | Hexane | 0.06 | 0.02 | ||||||||||||||||||||||||||
88 | 1330-20-7 | Xylene (mixture), including m-xylene, o-xylene, p-xylene | 0.031 | 0.011 | ||||||||||||||||||||||||||
89 | 7783-06-4 | Hydrogen sulfide | 0.00 | 0.00 |
A | B | C | D | E | F | G | H | I | J | K | L | |
---|---|---|---|---|---|---|---|---|---|---|---|---|
1 | Attachment B - Emission Calculations | |||||||||||
2 | Table B-5: VOC and TAC Emission from Truck Loading | |||||||||||
3 | ||||||||||||
4 | Toxics Emission Unit ID: | TLOAD1 | ||||||||||
5 | Emission Point: | TLOAD1 | ||||||||||
6 | Description: | Tank Truck Loading | ||||||||||
7 | ||||||||||||
8 | Product Loading VOC Emission Factor (EPA, AP-42, Section 5.2, July 2008) | |||||||||||
9 | ||||||||||||
10 | VOC EF= | (12.46 x S x P x M) | (AP-42 Section 5.2, Equation 1) | |||||||||
11 | T | |||||||||||
12 | ||||||||||||
13 | VOC EF= | VOC Emission factor for loading (lb/1000 gal) | ||||||||||
14 | S= | saturation factor (1 for submerged loading) | ||||||||||
15 | P= | true vapor pressure in psi at the loading temperature | ||||||||||
16 | M= | molecular weight of vapor | ||||||||||
17 | T= | temperature in Rankine | ||||||||||
18 | ||||||||||||
19 | Based on Maximum Emitting Product (flux) and Throughputs | |||||||||||
20 | ||||||||||||
21 | Product/Material | Throughput (gal/yr) | Location/Facility | S | P* | M** | T | VOC EF (lb/kgal) | VOC Emissions (lb/day) | VOC Emissions (lb/yr) | VOC Emissions (lb/day) | VOC Emissions (lb/yr) |
22 | Base Oil | 6,000,000.00 | Truck Loading Area | 1 | 0.05 | 130 | 528 | 0.153 | 2.52 | 920.34 | ||
23 | VGO | 6,000,000.00 | Truck Loading Area | 1 | 0.07 | 130 | 528 | 0.215 | 3.53 | 1,288.48 | ||
24 | Distillate (Light Ends) | 1,000,000.00 | Truck Loading Area | 1 | 0.09 | 130 | 528 | 0.276 | 0.76 | 276.10 | ||
25 | RFO (UMO) | 3,600,000.00 | Truck Loading Area | 1 | 0.08 | 130 | 528 | 0.245 | 2.42 | 883.53 | ||
26 | Flux*** | 1,200,000.00 | Truck Loading Area | 1 | 0.25 | 130 | 810 | 0.500 | 1.64 | 599.93 | 38.0 | 8898.9 |
27 | Totals | 10.87 | 3968.37 | |||||||||
28 | Maximum Annual Throughput | 17,800,000.00 | gal/yr | |||||||||
29 | Maximum Daily Throughput | 76,000 | gal/day | |||||||||
30 | ||||||||||||
31 | *Source: Vapor Pressure Testing, See Attachment E | |||||||||||
32 | **Source: AP-42 Table 7.1-2 (as Distallate Fuel Oil No. 2) | |||||||||||
33 | ||||||||||||
34 | ||||||||||||
35 | ||||||||||||
36 | Flux vp | ln(vp)=18.2891-12725.60/T | ||||||||||
37 | vp=mm Hg | |||||||||||
38 | 1 mm Hg=0.01934 psi | |||||||||||
39 | T=350 oF = 810 oR | (conservative estimate of max. loading temp., actual temp typically 250F) | ||||||||||
40 | vp=13.2 mm Hg = 0.25 psi | |||||||||||
41 | Ref: David Trumbore, Owens Corning, Winter 1999, Environmental Progress Journal, Table 2 | |||||||||||
42 | ||||||||||||
43 | ||||||||||||
44 | ||||||||||||
45 | Based on Maximum Emitting Product (flux) and Throughputs (for CAO ATEI) | |||||||||||
46 | Toxic Air Contaminant | CAS # | Speciation Factor wt % of TAC* | Emissions (lb/day) | Emissions (lb/yr) | Emissions (lb/gal) | Emissions (lb/day) | Emissions (lb/yr) | Emissions (lb/gal) | |||
47 | 2-Methyl naphthalene | 91-57-6 | 0.2860% | 3.11E-02 | 11.34954865 | 0.00000064 | 0.10866658 | 25.45085753 | 0.00000143 | |||
48 | Naphthalene | 91-20-3 | 0.1660% | 1.80E-02 | 6.58750026 | 0.00000037 | 0.06307221 | 14.77217605 | 0.00000083 | |||
49 | Phenol | 108-95-2 | 0.0000% | 0.00E+00 | 0 | 0 | 0 | 0 | 0 | |||
50 | Cresols (mixture), including m-cresol, o-cresol, p-cresol | 1319-77-3 | 0.0000% | 0.00E+00 | 0 | 0 | 0 | 0 | 0 |
51 | Benzene | 71-43-2 | 0.0232% | 2.52E-03 | 0.92066269 | 0.00000005 | 0.00881491 | 2.06454509 | 0.00000012 | |||
---|---|---|---|---|---|---|---|---|---|---|---|---|
52 | Ethyl benzene | 100-41-4 | 0.0589% | 6.40E-03 | 2.33737208 | 0.00000013 | 0.02237924 | 5.24145283 | 0.00000029 | |||
53 | Isopropylbenzene (Cumene) | 98-82-8 | 0.0122% | 1.33E-03 | 0.48414159 | 0.00000003 | 0.00463543 | 1.08566595 | 0.00000006 | |||
54 | Toluene | 108-88-3 | 0.2090% | 2.27E-02 | 8.29390094 | 0.00000047 | 0.0794102 | 18.59870358 | 0.00000104 | |||
55 | Hexane | 110-54-3 | 0.0345% | 3.75E-03 | 1.36908891 | 0.00000008 | 0.01310838 | 3.07012093 | 0.00000017 | |||
56 | Xylene (mixture), including m-xylene, o-xylene, p-xylene | 1330-20-7 | 0.3480% | 3.78E-02 | 13.80994031 | 0.00000078 | 0.13222367 | 30.9681763 | 0.00000174 | |||
57 | Hydrogen sulfide | 7783-06-4 | 0.0170% | 1.85E-03 | 0.67462352 | 0.00000004 | 0.0064592 | 1.51281321 | 0.00000008 | |||
58 | Totals | 0.13 | 45.83 | 0.44 | 102.76 |
A | B | C | D | E | F | G | H | |
---|---|---|---|---|---|---|---|---|
1 | Attachment B - Emission Calculations | |||||||
2 | Table B-6: TAC Emissions from Refinery Back-Up System | |||||||
3 | Emission Unit: | RCARBON | ||||||
4 | Emission Point: | RCARBON | ||||||
5 | Description: | Refinery vent carbon adsorption backup system | ||||||
7 | Max. Operating Parameters and Constants: | References | ||||||
8 | *Analytical Report by Test America for a similar PESCO Refinery (see Attachment G) | |||||||
9 | Duration of carbon venting | 8 | hr/day | |||||
10 | Hours per Year | 92 | hrs/year | (assume 1x per week) | ||||
12 | Refinery Vac System Flow Rate | 57 | ACFM | |||||
13 | Refinery Vac System Air Temp | 140 | F | |||||
14 | 333 | K | ||||||
16 | Stnd MV at Temp | 27.3 | L/Mol | |||||
17 | Carbon System DRE | 90% | ||||||
19 | Carbon Backup System Emissions | |||||||
20 | TAC | CAS # | ppmv* | MW | Inlet lb/hr | Outlet lb/hr | lb/day | lb/yr |
21 | Carbon Disulfide | 75-15-0 | 46.5 | 76.139 | 0.028 | 0.00276743 | 2.21E-02 | 2.55E-01 |
22 | Carbonyl Sulfide | 463-58-1 | 510 | 60.07 | 0.24 | 0.024 | 1.92E-01 | 2.20E+00 |
23 | Hydrogen Sulfide | 7783-06-4 | 7500 | 34.1 | 2.00 | 0.20 | 1.60E+00 | 1.84E+01 |
24 | Acetone | 67-64-1 | 390 | 58.08 | 0.18 | 0.018 | 1.42E-01 | 1.63E+00 |
25 | Benzene | 71-43-2 | 87 | 78.11 | 0.053 | 0.0053 | 4.25E-02 | 4.89E-01 |
26 | 2-Butanone (Methyl ethyl ketone) | 78-93-3 | 37 | 72.11 | 0.021 | 0.0021 | 1.67E-02 | 1.92E-01 |
27 | Chloroethane (Ethyl chloride) | 75-00-3 | 13 | 64.51 | 0.0066 | 0.00066 | 5.24E-03 | 6.03E-02 |
28 | Xylene (mixture), including m-xylene, o-xylene, p-xylene | 1330-20-7 | 21 | 106.16 | 0.017 | 0.0017 | 1.39E-02 | 1.60E-01 |